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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos 18162-48-6,872-50-4,Methylene Chloride,naphthalene,THF,Titanium Dioxide 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6
Product Name: 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms: 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;BRETTPHOS;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS: 1070663-78-3
MF: C35H53O2P
MW: 536.77
EINECS:
Product Categories: Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File: 1070663-78-3.mol
Melting point 191-193℃
Boiling point 607.7±55.0 °C(Predicted)
form crystal
color white
InChIKey WDVGNXKCFBOKDF-UHFFFAOYSA-N
Safety Information
Risk Statements 36/37/38
Safety Statements 26-37-60
WGK Germany nwg
TSCA No
MSDS Information
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis
Reactions
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
Uses Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Product Name: 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms: 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;BRETTPHOS;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS: 1070663-78-3
MF: C35H53O2P
MW: 536.77
EINECS:
Product Categories: Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File: 1070663-78-3.mol
Melting point 191-193℃
Boiling point 607.7±55.0 °C(Predicted)
form crystal
color white
InChIKey WDVGNXKCFBOKDF-UHFFFAOYSA-N
Safety Information
Risk Statements 36/37/38
Safety Statements 26-37-60
WGK Germany nwg
TSCA No
MSDS Information
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis
Reactions
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.
Uses Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
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