1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE

Superiority:

Product Name:    1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
Synonyms:    BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON;1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE;1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%;1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%;1,1'-Bis(di-tert-butylphosphin;98% DtBPF
CAS:    84680-95-5
MF:    C26H44FeP210*
MW:    474.42
EINECS:    626-167-5
Product Categories:    Achiral Phosphine;Aryl Phosphine;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Polydentate Phosphine Ligands
Mol File:    84680-95-5.mol

Melting point     181-182°C (dec.)
form     crystal
color     orange to red
Water Solubility     Insoluble in water.
InChIKey    FPLSJBJGQLJLSV-UHFFFAOYSA-N

Reaction    
Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.