CasNo.100165-88-6,(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL,(100165-88-6) Suppliers

1 Gram	Negotiable

Min.Order :1 Gram
Purity: 98%
Payment Terms : T/T,Other

Keywords

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL 100165-88-6 99%purity

Quick Details

Appearance:White powder
Application:intermediate
PackAge:according to the need of packing
ProductionCapacity:100|Kilogram|Day
Storage: dry, low temperature
Transportation:air sea or courier

Superiority:

Product Name:   (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

CAS:   100165-88-6
MF:   C48 H40 P2
MW:   678.78
EINECS:   1312995-182-4

Melting point    252-256 °C
alpha    -160° (c 0.5, C6H6)
Boiling point    754.4±60.0 °C(Predicted)
form    Powder
color    White
optical activity   [α]20/D -156°, c = 0.5 in benzene
Water Solubility    Insoluble in water.
InChIKey   IOPQYDKQISFMJI-UHFFFAOYSA-N

Reaction
Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
Ligand for palladium-catalyzed α-arylation of ketones.
Ligand for Cu-catalyzed asymmetric conjugate reduction.
Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
Enantioselective conjugate reduction of lactones and lactams.
Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.

Details:

Product Name:    (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

CAS:    100165-88-6
MF:    C48 H40 P2
MW:    678.78
EINECS:    1312995-182-4

Melting point     252-256 °C
alpha     -160° (c 0.5, C6H6)
Boiling point     754.4±60.0 °C(Predicted)
form     Powder
color     White
optical activity    [α]20/D -156°, c = 0.5 in benzene
Water Solubility     Insoluble in water.
InChIKey    IOPQYDKQISFMJI-UHFFFAOYSA-N

Reaction
Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
Ligand for palladium-catalyzed α-arylation of ketones.
Ligand for Cu-catalyzed asymmetric conjugate reduction.
Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
Enantioselective conjugate reduction of lactones and lactams.
Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.