tert-butylamine hydrobromide 60469-70-7 98% purity
Product Name: tert-butylamine hydrobromide
Synonyms: C(CH3)3NH3Br(t-BABr);tert-butylamine hydrobromide;Nsc225071;tert-Butylamine Hydrobromide
CAS: 60469-70-7
MF: C4H12BrN
MW: 154.04878
EINECS: 262-253-5
Product Categories:
Mol File: 60469-70-7.mol
Applications Bearing a tert-butyl bulky group, t-butylammonium bromide (tBABr) is commonly used to alter perovskite structures to promote material solubility and device stability - by making them less sensitive to moisture (compared to 3D methylammonium-based perovskites).
Plate-like 2D-phase crystallites were observed standing up between the 3D perovskite grains, and crystallinity was remarkably enhanced by precursors with bulky alkyl groups present in the perovskite structure.
Purification Methods Recrystallise the salt several times from absolute EtOH or by dissolving in absolute EtOH and adding Et2O slowly to crystallise the salt. Dry it thoroughly at 105o. [IR: Chenon & Sandorfy Can J Chem 36 1181 1958, Beilstein 4 IV 659.]
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