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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 169689-05-8 98% purity
Product Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms: (1S,2S)-(-)-1,2-TROST LIGAND;(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand;1S,2S- DHAC-Phenyl Trost Ligand;95% (S,S)-DACH-Phenyl Trost Ligand
CAS: 169689-05-8
MF: C44H40N2O2P2
MW: 690.76
Mol File: 169689-05-8.mol
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties
Melting point 134-136°C
alpha -134o (C=1 IN METHANOL)
Boiling point 817.0±65.0 °C(Predicted)
storage temp. Inert atmosphere,2-8°C
form Powder
pka 13.35±0.40(Predicted)
color white to off-white
optical activity [α]20/D -134°, c = 1 in methanol
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis
Reaction The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials
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