Copper quinolate

Details:

Melting point     240 °C (dec.)(lit.)
density     1,68 g/cm3
storage temp.     Inert atmosphere,2-8°C
Specific Gravity    1.68
Hydrolytic Sensitivity    4: no reaction with water under neutral conditions
InChIKey    YXLXNENXOJSQEI-UHFFFAOYSA-L
CAS DataBase Reference    10380-28-6(CAS DataBase Reference)
NIST Chemistry Reference    Copper 8-hydroxyquinolate(10380-28-6)
IARC    3 (Vol. 15, Sup 7) 1987
EPA Substance Registry System    Copper 8-quinolinolate (10380-28-6)
Safety Information
Hazard Codes     Xi
Risk Statements     36/37/38
Safety Statements     26-36
RIDADR     3077
WGK Germany     3
RTECS     VC5250000
Hazard Note     Irritant
TSCA     Yes
HazardClass     9
PackingGroup     III
HS Code     29334900
MSDS Information
Provider    Language
Cupric 8-hydroxyquinolate    English
SigmaAldrich    English
Copper quinolate Usage And Synthesis
Chemical Properties    Yellow solid
Chemical Properties    Yellow-green crystalline solid or powder. Odorless.
Uses    Fungicide and mildew-proofing of fabrics, analysis for copper.
Hazard    Toxic by ingestion. Questionable carcinogen.
Potential Exposure    Fungicide and microbiocide.
Shipping    UN3077 Environmentally Hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Incompatibilities    May form highly unstable acetylides. Decomposes on burning producing toxic and corrosive fumes including copper and nitrogen oxides
Waste Disposal    Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill Copper-containing wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. Details of copper recovery from a variety of industrial wastes have been published. If recovery is not feasible, the copper can be precipitated by the use of caustics and the sludge deposited in a chemical waste landfill. Recommendable Methods: Precipitation, solidification, landfill, discharge to sewer, & incineration. Peer-review: Precipitate copper with alkali, filter, solidify precipitate. (Do not use ammonia as alkali). Cation exchange will allow recovery of copper. Eluate from cation exchanger can be passed through anion exchanger to remove (or reduce) naphthenic acid content. Exhausted ion exchange resins can be landfilled. (Peer-review conclusions of an IRPTC expert consultation)
Copper quinolate Preparation Products And Raw materials
Raw materials    Sulfuric acid-->Glycerol-->Quinoline-->Cupric acetate monohydrate-->2-Aminophenol-->8-Hydroxyquinoline-->Cupric acetate
Preparation Products    2-Hydroxyphenylacetic acid