(+)-DIOP (4S,5S)-(+)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane(+)-DIOP(2S,3S)-(+)-2,3-O-Isopropylidene-2,3-Chemicalbookdihydroxy-1,4-bis(diphenylphosphino)butane;(+)-2,3-O-Isopropylidene-2,3-dihy (+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;(S,S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
Product Name: (+)-DIOP
Synonyms: (4S,5S)-(+)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (+)-DIOP (2S,3S)-(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane;(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosp;(S)-DIOP;(S,S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;1,1'-[[(4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[1,1-diphenyl-Phosphine;(4S,5S)-(+)-4,5-Bis(diphenylphosphinoMethyl)-2,2-diMethyl-1,3-dioxolane,(S,S)-DIOP.;(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;(S,S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
CAS: 37002-48-5
MF: C31H32O2P2
MW: 498.54
EINECS: 253-307-9
Product Categories: organophosphine ligand;Phosphine Ligands;Asymmetric Synthesis;Dioxanes & Dioxolanes;Dioxolanes;Synthetic Organic Chemistry;Chiral Phosphine;DIOP Series
Mol File: 37002-48-5.mol
(+)-DIOP Structure
(+)-DIOP Chemical Properties
Melting point 86-88 °C(lit.)
alpha +26° (c 2.0, CHCl3)
Boiling point 590.3±25.0 °C(Predicted)
storage temp. Store below +30°C.
form Powder
color White
Water Solubility Sparingly soluble in water at 25°C 2.1E-5 g/L.
Sensitive Air Sensitive
BRN 1630280
InChIKey VCHDBLPQYJAQSQ-LOYHVIPDSA-N
CAS DataBase Reference 37002-48-5
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
F 10-23
HS Code 29319090
Product Name: (+)-DIOP
Synonyms: (4S,5S)-(+)-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane (+)-DIOP (2S,3S)-(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane;(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosp;(S)-DIOP;(S,S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;1,1'-[[(4S,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[1,1-diphenyl-Phosphine;(4S,5S)-(+)-4,5-Bis(diphenylphosphinoMethyl)-2,2-diMethyl-1,3-dioxolane,(S,S)-DIOP.;(+)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;(S,S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
CAS: 37002-48-5
MF: C31H32O2P2
MW: 498.54
EINECS: 253-307-9
Product Categories: organophosphine ligand;Phosphine Ligands;Asymmetric Synthesis;Dioxanes & Dioxolanes;Dioxolanes;Synthetic Organic Chemistry;Chiral Phosphine;DIOP Series
Mol File: 37002-48-5.mol
(+)-DIOP Structure
(+)-DIOP Chemical Properties
Melting point 86-88 °C(lit.)
alpha +26° (c 2.0, CHCl3)
Boiling point 590.3±25.0 °C(Predicted)
storage temp. Store below +30°C.
form Powder
color White
Water Solubility Sparingly soluble in water at 25°C 2.1E-5 g/L.
Sensitive Air Sensitive
BRN 1630280
InChIKey VCHDBLPQYJAQSQ-LOYHVIPDSA-N
CAS DataBase Reference 37002-48-5
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
F 10-23
HS Code 29319090
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