4-TERT-BUTYLPYRIDINE

Superiority:

Product Name:    4-TERT-BUTYLPYRIDINE
Synonyms:    4-TERT-BUTYLPYRIDINE;4-T-BUTYLPYRIDINE;P-TERT-BUTYL PYRIDINE;4-tert-butoxypyridine;Pyridine,4-(1,1-diMethylethyl)-;4-tert-Butylpydrdine;4-tert-Butylpyridine 96%;Pyridine, 4-tert-butyl-
CAS:    3978-81-2
MF:    C9H13N
MW:    135.21
EINECS:    223-614-2
Product Categories:    C9 to C46;Heterocyclic Building Blocks;Pyridines
Mol File:    3978-81-2.mol
4-TERT-BUTYLPYRIDINE Structure
4-TERT-BUTYLPYRIDINE Chemical Properties
Melting point     -40°C(lit.)
Boiling point     196-197 °C (lit.)
density     0.923 g/mL at 25 °C (lit.)
refractive index     n20/D 1.495(lit.)
Fp     146 °F
storage temp.     Inert atmosphere,Room Temperature
pka    pK1: 5.99(+1) (25°C)
BRN     107594
InChIKey    YSHMQTRICHYLGF-UHFFFAOYSA-N
CAS DataBase Reference    3978-81-2(CAS DataBase Reference)
Safety Information
Hazard Codes     Xi
Risk Statements     36/37/38
Safety Statements     26-36
WGK Germany     3
HS Code     29333990
MSDS Information
Provider    Language
ACROS    English
SigmaAldrich    English
4-TERT-BUTYLPYRIDINE Usage And Synthesis
Application    
By introduction of Li-TFSI/TBP additives in poly-3-hexylthiophene HTM for CH3NH3PbI3/P3HT perovskite mesoscopic solar cells, great enhancement of the device efficiency from 5.7% to 13.7% was achieved [2].

Description    Together with our ultra pure LiTFSi and sublimed Spiro-MeOTAD, also with higher purity over 98.0%, 4-tert-Butylpyridine is an ideal condidate for your perovskite solar cells research.
Chemical Properties    clear colorless to slightly yellow liquid
Uses    
4-tert-Butylpyridine was used in composition of electrolyte for dye-sensitized solar cell.
General Description    
4-tert-Butylpyridine is specific additive of redox electrolyte in dye sensitized solar cells and dye-sensitized TiO2 solar cells.
Purification Methods    Dry 4-tert-butylpyridine over solid KOH and purify it by fractional distillation through an efficient column under dry N2. Its picrate has m 153.9-154o, and the hydrochloride has m 151.7-154.8o (from Me2CO). [Brown & Murphey J Am Chem Soc 73 3308 1951, IR: Arnett & Chawla J Am Chem Soc 100 214 1978, Kyle et al. J Chem Soc 4454 1960, Beilstein 20/6 V 123.]