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China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1
China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1
China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1
China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1
China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1

China Largest Manufacturer factory Supply Sodium Dimethyldithiocarbamate(SDD) CAS 128-04-1

Min.Order / FOB Price:Get Latest Price

1000 Kilogram

FOB Price:USD 1.0000 -2.0000

  • Min.Order :1000 Kilogram
  • Purity: 99%
  • Payment Terms : L/C,D/A,D/P,T/T,Other

Keywords

Sodium Dimethyldithiocarbamate Sodium Dimethyldithiocarbamate 128-04-1

Quick Details

  • Appearance:white powder
  • Application:Pharm chemicals industry
  • PackAge:25KG/Drum
  • ProductionCapacity:20|Metric Ton|Month
  • Storage:2-8°C
  • Transportation:By air /Sea/ coruier

Superiority:

                                PRODUCT DETAILS       

Sodium dimethyldithiocarbamate Basic information
Product Name: Sodium dimethyldithiocarbamate
Synonyms: Dimethyl dithiocarbamate, sodium salt;Dimethyldithiocarbamic acid sodium salt, 40% solution;Sodiumdimethyldithiocarbamat;Sodium Dimethyl Dithiocarbamate (Sdd/Sdmc);sodium dimethyldithiocarbamate solution;SMEC(MICTUREOF[128-04-1]AND[142-59-6]);Sodium N,N-dimethyldithiocarbamate 95%;(Dimethyldithiocarbamato)sodium
CAS: 128-04-1
MF: C3H6NNaS2
MW: 143.21
EINECS: 204-876-7
Product Categories: Aliphatics;Classes of Metal Compounds;Pharmaceutical Intermediates;Na (Sodium) Compounds (excluding simple sodium salts);Typical Metal Compounds;Antisepsis Agent;Syntheses Material
Mol File: 128-04-1.mol
Sodium dimethyldithiocarbamate Structure
 
Sodium dimethyldithiocarbamate Chemical Properties
Melting point  120-122 °C (dec.)(lit.)
density  1.17
storage temp.  0-6°C
Specific Gravity 1.18
Hydrolytic Sensitivity 0: forms stable aqueous solutions
BRN  3569024
InChIKey NQVBYQPOGVWUPK-UHFFFAOYSA-M
CAS DataBase Reference 128-04-1(CAS DataBase Reference)
EPA Substance Registry System Sodium dimethyldithiocarbamate (128-04-1)
 
Safety Information
Hazard Codes  Xn,N
Risk Statements  22-36-50
Safety Statements  26-36-61
RIDADR  UN 3082 9 / PGIII
WGK Germany  -
RTECS  FD3500000
21
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29302000
Hazardous Substances Data 128-04-1(Hazardous Substances Data)
MSDS Information
Provider Language
Dimethyldithiocarbamic acid sodium salt English
SigmaAldrich English
ACROS English
 
Sodium dimethyldithiocarbamate Usage And Synthesis
Description Dithiocarbamates (DCs) are a well-known group of pesticides which have been used to control a number of species belonging to taxonomically different groups, e.g., bacteria, fungi, nematodes, and molluscs for over 60 years. The first integrated product containing sodium dimethyldithiocarbamate (SDMC) was registered in 1949.
Chemical Properties CLEAR YELLOW SOLUTION
Chemical Properties Sodium dimethyldithiocarbamate is a clear yellow liquid or yellow crystalline solid
Uses SDMC is used as a disinfectant, corrosion inhibitor, coagulant, vulcanizing agent, chelating agent, and fungicide. SDMC is used in water treatment, the rubber industry, and is a registered biocide for cutting oils and aqueous systems in industries such as leather tanning and paper manufacturing. It is also used as an antimicrobial agent in paints. DCs generally are able to function as metal chelators and have been used in metal finishing operations and wastewater treatments to enhance the precipitation of metals. As a free radical inhibitor, it has been used in the rubber industry to rapidly stop the polymerization of synthesis. It is also used as a biocide for cutting oils and aqueous systems such as leather tanning and paper manufacturing.
Uses Dimethyldithiocarbamic Acid Sodium Salt was used in studies to develop removal of heavy metals from water by sulfide precipitation.
General Description Crystals or liquid. Becomes anhydrous at 266°F.
Air & Water Reactions Slowly decomposes in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile Flammable gases are generated by the combination with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.
Health Hazard ACUTE/CHRONIC HAZARDS: When heated to decomposition it emits very toxic fumes.
Fire Hazard Flash point data for Sodium dimethyldithiocarbamate are not available. Sodium dimethyldithiocarbamate is probably not flammable.
Safety Profile Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, SOx, and Na2O. See also CARBAMATES.
Potential Exposure The slow release of poisonous gases from hydrolysis of many thio and dithiocarbamates requires the use of respirators during handling. Used as an antimicrobial/fungicidal agent in paints, water treatment; a registered biocide for cutting oils and aqueous systems in industries such as leather tanning and paper manufacturing. Used in the rubber industry as a vulcanization accelerator for making synthetic and natural rubbers (i.e., butadiene rubber, latex). Used as a fungicide on melons (tolerance set as 25 ppm). Also used as an indirect food additive for use only as a component of adhesives.
Environmental Fate Routes and Pathways and Relevant Physicochemical Properties
The estimated pKa of SDMC is 5.4, indicating that this compound will primarily exist in the dissociated form at environmentally relevant pHs. If released to air, SDMC will exist solely in the particulate phase in the ambient atmosphere, since it is a salt and will be nonvolatile. Due to the short chemical lifetime of SDMC in air, it is not expected to accumulate in air or transported in the gaseous phase over long distances. Furthermore, based on the estimated Henry’s law constant at 25°C = 6.972 1015 atmm3 mol-1at 20 °C for it and Log Pow equal to 2.41, air will not be an environmental compartment of concern and sodium N,N-dimethyldithiocarbamate can be classified as a nonadsorbed substance.
Partition Behavior in Water, Sediment, and Soil
The Koc of SDMC is estimated as 2.2, suggesting that SDMC is expected to have very high mobility in soil and is not adsorbed to suspended solids or sediment.
Environmental Persistency
Particulate-phase SDMC will be removed from the atmosphere by wet and dry depositions. Photolysis in aqueous solution and soil was found to be an important degradation process for SDMC. Depending on the geographical latitude (30–50 N) and the climatic season, the calculated environmental half-lives of SDMC range from 0.3 to 2.26 days. Hydrolysis of SDMC occurs at neutral and acidic pHs. The hydrolysis half-life of 18 min, 25.9, and 433.3 h was reported for SDMC at pH 5, 7, and 9, respectively. The products of degradation are less toxic than the product itself. 14C-SDMC is rapidly photodegraded in buffered solution at pH 9 with a calculated experimental halflife of 0.79 days, corresponding to 19 h. Direct photolysis in surface water and soil is an important degradation process for SDMC.
Shipping UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Purification Methods Crystallise it from a small volume of H2O, or dissolve it in the minimum volume of H2O and add cold Me2CO, collect it and dry it in air. The solubility in Me2CO is 50g/400mL. The dihydrate loses H2O on heating at 115o to give the hemi-hydrate which decomposes on further heating [Kulka Can J Chem 34 1096 1956]. [Beilstein 4 IV 233.]
Toxicity evaluation Dimethyldithiocarbamates in general are metabolized to carbon disulfide, a known animal and human neurotoxicant having a common neuropathic effect by a common active metabolite. The distal peripheral and peripheral neuropathies induced by DCs are postulated to arise via a common mechanism of toxicity, that is, the formation of carbon disulfide. Chronic exposure increases brain neurotransmitters and stimulates sex hormone cycle, especially in women.
Incompatibilities Slowly decomposes in water, forming carbon disulfide, oxides of sulfur and nitrogen, hydrogen sulfide, ammonia, and amines, including methylamine; this decomposition is accelerated in the presence of acids. Flammable gases are generated by the combination with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides. Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with carboxylic acid acids, peroxides, and acid halides.
Waste Disposal Dispose of contents and container to an approved waste disposal plant. All federal, state, and local environmental regulations must be observed.
 
Sodium dimethyldithiocarbamate Preparation Products And Raw materials
Raw materials Sodium hydroxide-->Carbon disulfide-->Dimethylamine
Preparation Products Tetramethylthiuram Disulfide-->Zinc dimethyldithiocarbamate-->AsoMate-->2-Mercapto-5-methylbenzoxazole-->5-Chloro-2-mercaptobenzothiazole
 
 

 

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Leader Biochemical Group is a large leader incorporated industry manufacturers and suppliers of advanced refined raw materials From the year of 1996 when our factory was put into production to year of 2020, our group has successively invested in more than 52 factories with shares and subordinates.We focus on manufacture Pharm & chemicals, functional active ingredients, nutritional Ingredients, health care products, cosmetics, pharmaceutical and refined feed, oil, natural plant ingredients industries to provide top quality of GMP standards products.All the invested factories' product lines cover API and intermediates, vitamins, amino acids, plant extracts, daily chemical products, cosmetics raw materials, nutrition and health care products, food additives, feed additives, essential oil products, fine chemical products and agricultural chemical raw materials And flavors and fragrances. Especially in the field of vitamins, amino acids, pharmaceutical raw materials and cosmetic raw materials, we have more than 20 years of production and sales experience. All products meet the requirements of high international export standards and have been recognized by customers all over the world. Our manufacture basement & R&D center located in National Aerospace Economic & Technical Development Zone Xi`an Shaanxi China. Now not only relying on self-cultivation and development as well as maintains good cooperative relations with many famous research institutes and universities in China. Now, we have closely cooperation with Shanghai Institute of Organic Chemistry of Chinese Academy of Science, Beijing Institute of Material Medical of Chinese Academy of Medical Science, China Pharmaceutical University, Zhejiang University. Closely cooperation with them not only integrating Science and technology resources, but also increasing the R&D speed and improving our R&D power. Offering Powerful Tech supporting Platform for group development. Keep serve the manufacture and the market as the R&D central task, focus on the technical research.  Now there are 3 technology R & D platforms including biological extract, microorganism fermentation and chemical synthesis, and can independently research and develop kinds of difficult APIs and pharmaceutical intermediates. With the strong support of China State Institute of Pharmaceutical Industry (hereinafter short for CSIPI), earlier known as Shanghai Institute of Pharmaceutical Industry (SIPI), we have unique advantages in the R & D and industrialization of high-grade, precision and advanced products.  Now our Group technical force is abundant, existing staff more that 1000 people, senior professional and technical staff accounted for more than 50% of the total number of employees, including 15 PhD research and development personnel, 5 master′ S degree in technical and management personnel 9 people. We have advanced equipment like fermentation equipment and technology also extraction, isolation, purification, synthesis with rich production experience and strict quality control system, According to the GMP required, quickly transforming the R&D results to industrial production in time, it is our advantages and our products are exported to North and South America, Europe, Middle East, Africa, and other five continents and scale the forefront in the nation, won good international reputation.  We believe only good quality can bring good cooperation, quality is our key spirit during our production, we are warmly welcome clients and partner from all over the world contact us for everlasting cooperation, Leader will be your strong, sincere and reliable partner in China.

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                                                       Product information

Sodium dimethyldithiocarbamate Basic information
Product Name: Sodium dimethyldithiocarbamate
Synonyms: Dimethyl dithiocarbamate, sodium salt;Dimethyldithiocarbamic acid sodium salt, 40% solution;Sodiumdimethyldithiocarbamat;Sodium Dimethyl Dithiocarbamate (Sdd/Sdmc);sodium dimethyldithiocarbamate solution;SMEC(MICTUREOF[128-04-1]AND[142-59-6]);Sodium N,N-dimethyldithiocarbamate 95%;(Dimethyldithiocarbamato)sodium
CAS: 128-04-1
MF: C3H6NNaS2
MW: 143.21
EINECS: 204-876-7
Product Categories: Aliphatics;Classes of Metal Compounds;Pharmaceutical Intermediates;Na (Sodium) Compounds (excluding simple sodium salts);Typical Metal Compounds;Antisepsis Agent;Syntheses Material
Mol File: 128-04-1.mol
Sodium dimethyldithiocarbamate Structure
 
Sodium dimethyldithiocarbamate Chemical Properties
Melting point  120-122 °C (dec.)(lit.)
density  1.17
storage temp.  0-6°C
Specific Gravity 1.18
Hydrolytic Sensitivity 0: forms stable aqueous solutions
BRN  3569024
InChIKey NQVBYQPOGVWUPK-UHFFFAOYSA-M
CAS DataBase Reference 128-04-1(CAS DataBase Reference)
EPA Substance Registry System Sodium dimethyldithiocarbamate (128-04-1)
 
Safety Information
Hazard Codes  Xn,N
Risk Statements  22-36-50
Safety Statements  26-36-61
RIDADR  UN 3082 9 / PGIII
WGK Germany  -
RTECS  FD3500000
21
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29302000
Hazardous Substances Data 128-04-1(Hazardous Substances Data)
MSDS Information
Provider Language
Dimethyldithiocarbamic acid sodium salt English
SigmaAldrich English
ACROS English
 
Sodium dimethyldithiocarbamate Usage And Synthesis
Description Dithiocarbamates (DCs) are a well-known group of pesticides which have been used to control a number of species belonging to taxonomically different groups, e.g., bacteria, fungi, nematodes, and molluscs for over 60 years. The first integrated product containing sodium dimethyldithiocarbamate (SDMC) was registered in 1949.
Chemical Properties CLEAR YELLOW SOLUTION
Chemical Properties Sodium dimethyldithiocarbamate is a clear yellow liquid or yellow crystalline solid
Uses SDMC is used as a disinfectant, corrosion inhibitor, coagulant, vulcanizing agent, chelating agent, and fungicide. SDMC is used in water treatment, the rubber industry, and is a registered biocide for cutting oils and aqueous systems in industries such as leather tanning and paper manufacturing. It is also used as an antimicrobial agent in paints. DCs generally are able to function as metal chelators and have been used in metal finishing operations and wastewater treatments to enhance the precipitation of metals. As a free radical inhibitor, it has been used in the rubber industry to rapidly stop the polymerization of synthesis. It is also used as a biocide for cutting oils and aqueous systems such as leather tanning and paper manufacturing.
Uses Dimethyldithiocarbamic Acid Sodium Salt was used in studies to develop removal of heavy metals from water by sulfide precipitation.
General Description Crystals or liquid. Becomes anhydrous at 266°F.
Air & Water Reactions Slowly decomposes in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile Flammable gases are generated by the combination with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides.
Health Hazard ACUTE/CHRONIC HAZARDS: When heated to decomposition it emits very toxic fumes.
Fire Hazard Flash point data for Sodium dimethyldithiocarbamate are not available. Sodium dimethyldithiocarbamate is probably not flammable.
Safety Profile Moderately toxic by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, SOx, and Na2O. See also CARBAMATES.
Potential Exposure The slow release of poisonous gases from hydrolysis of many thio and dithiocarbamates requires the use of respirators during handling. Used as an antimicrobial/fungicidal agent in paints, water treatment; a registered biocide for cutting oils and aqueous systems in industries such as leather tanning and paper manufacturing. Used in the rubber industry as a vulcanization accelerator for making synthetic and natural rubbers (i.e., butadiene rubber, latex). Used as a fungicide on melons (tolerance set as 25 ppm). Also used as an indirect food additive for use only as a component of adhesives.
Environmental Fate Routes and Pathways and Relevant Physicochemical Properties
The estimated pKa of SDMC is 5.4, indicating that this compound will primarily exist in the dissociated form at environmentally relevant pHs. If released to air, SDMC will exist solely in the particulate phase in the ambient atmosphere, since it is a salt and will be nonvolatile. Due to the short chemical lifetime of SDMC in air, it is not expected to accumulate in air or transported in the gaseous phase over long distances. Furthermore, based on the estimated Henry’s law constant at 25°C = 6.972 1015 atmm3 mol-1at 20 °C for it and Log Pow equal to 2.41, air will not be an environmental compartment of concern and sodium N,N-dimethyldithiocarbamate can be classified as a nonadsorbed substance.
Partition Behavior in Water, Sediment, and Soil
The Koc of SDMC is estimated as 2.2, suggesting that SDMC is expected to have very high mobility in soil and is not adsorbed to suspended solids or sediment.
Environmental Persistency
Particulate-phase SDMC will be removed from the atmosphere by wet and dry depositions. Photolysis in aqueous solution and soil was found to be an important degradation process for SDMC. Depending on the geographical latitude (30–50 N) and the climatic season, the calculated environmental half-lives of SDMC range from 0.3 to 2.26 days. Hydrolysis of SDMC occurs at neutral and acidic pHs. The hydrolysis half-life of 18 min, 25.9, and 433.3 h was reported for SDMC at pH 5, 7, and 9, respectively. The products of degradation are less toxic than the product itself. 14C-SDMC is rapidly photodegraded in buffered solution at pH 9 with a calculated experimental halflife of 0.79 days, corresponding to 19 h. Direct photolysis in surface water and soil is an important degradation process for SDMC.
Shipping UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Purification Methods Crystallise it from a small volume of H2O, or dissolve it in the minimum volume of H2O and add cold Me2CO, collect it and dry it in air. The solubility in Me2CO is 50g/400mL. The dihydrate loses H2O on heating at 115o to give the hemi-hydrate which decomposes on further heating [Kulka Can J Chem 34 1096 1956]. [Beilstein 4 IV 233.]
Toxicity evaluation Dimethyldithiocarbamates in general are metabolized to carbon disulfide, a known animal and human neurotoxicant having a common neuropathic effect by a common active metabolite. The distal peripheral and peripheral neuropathies induced by DCs are postulated to arise via a common mechanism of toxicity, that is, the formation of carbon disulfide. Chronic exposure increases brain neurotransmitters and stimulates sex hormone cycle, especially in women.
Incompatibilities Slowly decomposes in water, forming carbon disulfide, oxides of sulfur and nitrogen, hydrogen sulfide, ammonia, and amines, including methylamine; this decomposition is accelerated in the presence of acids. Flammable gases are generated by the combination with aldehydes, nitrides, and hydrides. Incompatible with acids, peroxides, and acid halides. Thiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with carboxylic acid acids, peroxides, and acid halides.
Waste Disposal Dispose of contents and container to an approved waste disposal plant. All federal, state, and local environmental regulations must be observed.
 
Sodium dimethyldithiocarbamate Preparation Products And Raw materials
Raw materials Sodium hydroxide-->Carbon disulfide-->Dimethylamine
Preparation Products Tetramethylthiuram Disulfide-->Zinc dimethyldithiocarbamate-->AsoMate-->2-Mercapto-5-methylbenzoxazole-->5-Chloro-2-mercaptobenzothiazole

 

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