Diglycol Monobutyl Ether Acetate (BDGA)

Superiority:

SAFETY DATA SHEETS

According to the UN GHS revision 10

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1GHS Product identifier

Product name	2-(2-butoxyethoxy)ethyl acetate

1.2Other means of identification

Product number	-
Other names	ETHANOL,2-(2-BUTOXYETHOXY)-, 1-ACETATE; DIETHYLENEGLYCOLMONOBUTYLETHERACETATE; DIETHYLENEGLYCOL MONOBUTYL ETHER ACETATE

1.3Recommended use of the chemical and restrictions on use

Identified uses	Industrial and scientific research use.
Uses advised against	no data available

 

SECTION 2: Hazard identification

 

2.1Classification of the substance or mixture

Not classified.

2.2GHS label elements, including precautionary statements

Pictogram(s)	No symbol.
Signal word	No signal word
Hazard statement(s)	none
Precautionary statement(s)
Prevention	none
Response	none
Storage	none
Disposal	none

2.3Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
2-(2-butoxyethoxy)ethyl acetate	2-(2-butoxyethoxy)ethyl acetate	124-17-4	204-685-9	100%

SECTION 4: First-aid measures

4.1Description of necessary first-aid measures

If inhaled

Fresh air, rest.

Following skin contact

Rinse skin with plenty of water or shower.

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Rinse mouth.

4.2Most important symptoms/effects, acute and delayed

Prolonged breathing of vapor may cause irritation and nausea. Contact with liquid may cause mild irritation of eyes and skin. Can be absorbed through skin in toxic amounts. (USCG, 1999)

4.3Indication of immediate medical attention and special treatment needed, if necessary

Absorption, Distribution and Excretion

When diethylene glycol butyl ether (DGBE) and diethylene glycol monobutyl ether acetate (DGBEA) were applied to the skin for 5 min then washed, most (90%) of the material was recovered. When applied under occlusion for 24 hr, the calculated absorption rates for DGBEA were similar (1.58, 1.28 mg/cm sq/hr for males and females, respectively; mean=1.43) to those of DGBE (0.73, 1.46; mean=1.10 mg/cm sq/hr).

SECTION 5: Fire-fighting measures

5.1Suitable extinguishing media

Foam, carbon dioxide, dry chem...

5.2Specific hazards arising from the chemical

Combustible.

5.3Special protective actions for fire-fighters

Use water spray, powder, alcohol-resistant foam, carbon dioxide.

SECTION 6: Accidental release measures

6.1Personal precautions, protective equipment and emergency procedures

Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.2Environmental precautions

Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.

6.3Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1Precautions for safe handling

NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2Conditions for safe storage, including any incompatibilities

Separated from strong oxidants. Ventilation along the floor.

SECTION 8: Exposure controls/personal protection

8.1Control parameters

Occupational Exposure limit values

MAK: 85 mg/m3, 10 ppm; peak limitation category: I(1); pregnancy risk group: C

Biological limit values

no data available

8.2Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety spectacles.

Skin protection

Protective gloves.

Respiratory protection

Use ventilation.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state	Liquid. Not applicable.
Colour	Colourless.
Odour	MILD, NOT UNPLEASANT ODOR
Melting point/freezing point	< -70 °C. Atm. press.:1 atm.
Boiling point or initial boiling point and boiling range	245 °C. Atm. press.:1 atm.
Flammability	Combustible.
Lower and upper explosion limit/flammability limit	Lower flammable limit: 0.76% by volume; Upper flammable limit:5.0% by volume
Flash point	116 °C. Atm. press.:1 atm.
Auto-ignition temperature	290 °C. Atm. press.:1 atm.
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	kinematic viscosity (in mm²/s) = 4.68. Temperature:10.0°C.;kinematic viscosity (in mm²/s) = 3.519. Temperature:20°C.;kinematic viscosity (in mm²/s) = 2.771. Temperature:30.0°C.
Solubility	Very soluble in acetone, ethyl ether, ethanol
Partition coefficient n-octanol/water	log Pow = 1.7. Temperature:23 °C.
Vapour pressure	0.1 hPa. Temperature:46 °C. Remarks:Lowest value measured.;Ca. 0.005 hPa. Temperature:20 °C. Remarks:Extrapolated.
Density and/or relative density	976.5 kg/m³. Temperature:20 °C.
Relative vapour density	(air = 1): 7.0
Particle characteristics	no data available

SECTION 10: Stability and reactivity

10.1Reactivity

The substance can presumably form explosive peroxides. Reacts with strong oxidants.

10.2Chemical stability

no data available

10.3Possibility of hazardous reactions

CombustibleEsters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

10.4Conditions to avoid

no data available

10.5Incompatible materials

Glycol ethers, glycols, ketones, and alcohols undergo violent decomposition in contact with 68-72% perchloric acid

10.6Hazardous decomposition products

When heated to decomposition it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

Acute toxicity

• Oral: LD50 - rat (male) - 11 920 mg/kg bw.
• Inhalation: LC0 - rat (male/female) - > 400 ppm.
• Dermal: LD50 - rabbit - 5.75 mL/kg bw.

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

The substance is mildly irritating to the eyes and skin.

STOT-repeated exposure

The substance defats the skin, which may cause dryness or cracking.

Aspiration hazard

No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

SECTION 12: Ecological information

12.1Toxicity

• Toxicity to fish: LC50 - Danio rerio (previous name: Brachydanio rerio) - > 50 - < 70 mg/L - 96 h.
• Toxicity to daphnia and other aquatic invertebrates: LC50 - Daphnia magna - 664 mg/L - 48 h.
• Toxicity to algae: EC50 - Pseudokirchneriella subcapitata (previous names: Raphidocelis subcapitata, Selenastrum capricornutum) - 1 570 mg/L - 72 h.
• Toxicity to microorganisms: EC0 - activated sludge, industrial - 1 575 mg/L - 30 min. Remarks:Respiration rate.

12.2Persistence and degradability

AEROBIC: Diethyleneglycol monobutyl ether acetate, present at 100 mg/L, reached 100% of its theoretical BOD in four weeks using an activated sludge inoculum at 30 mg/L and the Japanese MITI test(1). A 20-day biodegradation study using 2.5 ppm diethyleneglycol monobutyl ether acetate in BOD bottle mineralization dilution water and settled sewage seed at 20 deg C gave a theoretical BOD of 67.6%(2). The normal BOD curve for diethyleneglycol monobutyl ether acetate seeded with microorganisms from domestic sewage shows slow development that usually requires more than five days for the BOD value to reach 20 percent of the theoretical oxygen demand (40% at 14 days)(3). Acclimated microorganisms from the Kanawana River biodegrade diethyleneglycol monobutyl ether acetate much faster with theoretical BOD values of 84% after 10 days and 58% after 10 days using microorganisms acclimated for 59 and 28 days, respectively(3). The difficulty in oxidizing diethyleneglycol monobutyl ether acetate is apparently related to the butoxy group(3). Diethyleneglycol monobutyl ether acetate had theoretical BOD rates of 13.3, 18.4, 24.6, and 67.0% for BOD 5, 10, 15, and 20 days, respectively(4).

12.3Bioaccumulative potential

An estimated BCF of 2 was calculated in fish for diethyleneglycol monobutyl ether acetate(SRC), using an estimated log Kow of 1.30(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

12.4Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of diethyleneglycol monobutyl ether acetate can be estimated to be 10(SRC). According to a classification scheme(2), this estimated Koc value suggests that diethyleneglycol monobutyl ether acetate is expected to have very high mobility in soil(SRC).

12.5Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1UN Number

ADR/RID: Not dangerous goods. (For reference only, please check.)

IMDG: Not dangerous goods. (For reference only, please check.)

IATA: Not dangerous goods. (For reference only, please check.)

14.2UN Proper Shipping Name

ADR/RID: Not dangerous goods. (For reference only, please check.)

IMDG: Not dangerous goods. (For reference only, please check.)

IATA: Not dangerous goods. (For reference only, please check.)

14.3Transport hazard class(es)

ADR/RID: Not dangerous goods. (For reference only, please check.)

IMDG: Not dangerous goods. (For reference only, please check.)

IATA: Not dangerous goods. (For reference only, please check.)

14.4Packing group, if applicable

ADR/RID: Not dangerous goods. (For reference only, please check.)

IMDG: Not dangerous goods. (For reference only, please check.)

IATA: Not dangerous goods. (For reference only, please check.)

14.5Environmental hazards

ADR/RID: No

IMDG: No

IATA: No

14.6Special precautions for user

no data available

14.7Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
2-(2-butoxyethoxy)ethyl acetate	2-(2-butoxyethoxy)ethyl acetate	124-17-4	204-685-9
European Inventory of Existing Commercial Chemical Substances (EINECS)			Listed.
EC Inventory			Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Listed.
China Catalog of Hazardous chemicals 2015			Not Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Listed.
Vietnam National Chemical Inventory			Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Listed.
Korea Existing Chemicals List (KECL)			Listed.

SECTION 16: Other information

Information on revision

Creation Date	July 15, 2019
Revision Date	July 15, 2019

Abbreviations and acronyms

• CAS: Chemical Abstracts Service
• ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
• RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
• IMDG: International Maritime Dangerous Goods
• IATA: International Air Transportation Association
• TWA: Time Weighted Average
• STEL: Short term exposure limit
• LC50: Lethal Concentration 50%
• LD50: Lethal Dose 50%
• EC50: Effective Concentration 50%

 

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