Superiority:

SAFETY DATA SHEETS

According to the UN GHS revision 9

Version: 1.0

Creation Date: July 15, 2019

Revision Date: July 15, 2019

SECTION 1: Identification

1.1GHS Product identifier

Product name	Turpentine, oil

1.2Other means of identification

Product number	-
Other names	-

1.3Recommended use of the chemical and restrictions on use

Identified uses	Industrial and scientific research use.
Uses advised against	no data available

SECTION 2: Hazard identification

2.1Classification of the substance or mixture

Flammable liquids, Category 3

Acute toxicity - Category 4, Oral

Acute toxicity - Category 4, Dermal

Skin irritation, Category 2

Eye irritation, Category 2

Skin sensitization, Category 1

Acute toxicity - Category 4, Inhalation

Aspiration hazard, Category 1

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

2.2GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H226 Flammable liquid and vapour H302 Harmful if swallowed H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H317 May cause an allergic skin reaction H332 Harmful if inhaled H304 May be fatal if swallowed and enters airways H411 Toxic to aquatic life with long lasting effects
Precautionary statement(s)
Prevention	P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment.
Response	P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. P370+P378 In case of fire: Use ... to extinguish. P301+P317 IF SWALLOWED: Get medical help. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of water/... P317 Get medical help. P321 Specific treatment (see ... on this label). P362+P364 Take off contaminated clothing and wash it before reuse. P332+P317 If skin irritation occurs: Get medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P317 If skin irritation or rash occurs: Get medical help. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301+P316 IF SWALLOWED: Get emergency medical help immediately. P331 Do NOT induce vomiting. P391 Collect spillage.
Storage	P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

2.3Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

3.1Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
Turpentine, oil	Turpentine, oil	8006-64-2	232-350-7	100%

SECTION 4: First-aid measures

4.1Description of necessary first-aid measures

If inhaled

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

Following skin contact

Remove contaminated clothes. Rinse and then wash skin with water and soap.

Following eye contact

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Following ingestion

Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .

4.2Most important symptoms/effects, acute and delayed

no data available

4.3Indication of immediate medical attention and special treatment needed, if necessary

no data available

SECTION 5: Fire-fighting measures

5.1Suitable extinguishing media

Use dry chemical, carbon dioxide or alcohol-resistant foam.

5.2Specific hazards arising from the chemical

Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 30°C explosive vapour/air mixtures may be formed.

5.3Special protective actions for fire-fighters

Use foam, dry powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

SECTION 6: Accidental release measures

6.1Personal precautions, protective equipment and emergency procedures

Cover the spilled material with dry earth, sand or other non-combustible material. Ventilation. Remove all ignition sources. Do NOT wash away into sewer. Sweep spilled substance into covered containers. Then store and dispose of according to local regulations. Personal protection: self-contained breathing apparatus. Do NOT let this chemical enter the environment.

6.2Environmental precautions

Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

6.3Methods and materials for containment and cleaning up

Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

SECTION 7: Handling and storage

7.1Precautions for safe handling

NO open flames, NO sparks and NO smoking. Above 30°C use a closed system, ventilation and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

7.2Conditions for safe storage, including any incompatibilities

Fireproof. Separated from strong oxidants and incompatible materials. See Chemical Dangers. Cool. Keep in a well-ventilated room.

SECTION 8: Exposure controls/personal protection

8.1Control parameters

Occupational Exposure limit values

TLV: 20 ppm as TWA; (SEN); A4 (not classifiable as a human carcinogen).MAK: 28 mg/m3, 5 ppm; peak limitation category: II(2); skin absorption (H); sensitization of skin (SH); pregnancy risk group: D

Biological limit values

no data available

8.2Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

8.3Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety spectacles or eye protection in combination with breathing protection.

Skin protection

Protective gloves. Protective clothing.

Respiratory protection

Use ventilation, local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

Physical state	Liquid.
Colour	Colourless liquid.
Odour	no data available
Melting point/freezing point	-60 - -50 °C.
Boiling point or initial boiling point and boiling range	154 - 170 °C. Remarks:The data was obtained from a reliable handbook which was subject to peer review, details on the atmospheric pressure was not stated.
Flammability	no data available
Lower and upper explosion limit/flammability limit	no data available
Flash point	24 °C. Atm. press.:100.8 - 101.8 kPa.
Auto-ignition temperature	270 °C. Atm. press.:99.44 - 99.52 kPa.
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	no data available
Solubility	Insoluble in water
Partition coefficient n-octanol/water	log Pow = 0.8 - 6.3. Temperature:20 °C. Remarks:Predicted log Kow for all constituents of the substance.;log Pow = 0.8 - 6.3. Temperature:20 °C. Remarks:Predicted log Kow of identified 'blocks' in the constituents of the substance.
Vapour pressure	0.057 - 200 000 Pa. Temperature:25 °C. Remarks:Predicted vapour pressure for constituents of TOPP.;2 600 Pa. Temperature:25 °C. Remarks:Predicted vapour pressure for TOPP as a whole substance.
Density and/or relative density	864 kg/m³. Temperature:20 °C.;860 kg/m³. Temperature:25 °C.
Relative vapour density	no data available
Particle characteristics	no data available

SECTION 10: Stability and reactivity

10.1Reactivity

no data available

10.2Chemical stability

no data available

10.3Possibility of hazardous reactions

On combustion, forms toxic fumes including carbon monoxide. Decomposes slowly under the influence of air and light. This produces oxidation products that are more toxic or irritating than turpentine itself. Reacts violently with oxidants, halogens, combustible substances and mineral acids. Attacks plastics and rubber.

10.4Conditions to avoid

no data available

10.5Incompatible materials

no data available

10.6Hazardous decomposition products

no data available

SECTION 11: Toxicological information

Acute toxicity

• Oral: LD50 - rat (male) - 4.6 mL/kg bw.
• Inhalation: no data available
• Dermal: LD50 - rabbit - > 2 000 mg/kg bw.

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

The vapour is irritating to the eyes, skin and respiratory tract. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The substance may cause effects on the central nervous system, bladder and kidneys. This may result in irritability, convulsions and kidney impairment. Exposure at high levels could cause tachycardia, unconsciousness, respiratory failure and death.

STOT-repeated exposure

Repeated or prolonged contact may cause skin sensitization. The substance defats the skin, which may cause dryness or cracking.

Aspiration hazard

A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

SECTION 12: Ecological information

12.1Toxicity

• Toxicity to fish: LL50 - Danio rerio (previous name: Brachydanio rerio) - 29 mg/L - 96 h. Remarks:Water-accommodated fraction loading rate.
• Toxicity to daphnia and other aquatic invertebrates: NOELR - Daphnia magna - ca. 1 mg/L - 48 h. Remarks:Water-accommodated fraction loading rate.
• Toxicity to algae: EL50 - Desmodesmus subspicatus (previous name: Scenedesmus subspicatus) - 17.1 mg/L - 72 h.
• Toxicity to microorganisms: no data available

12.2Persistence and degradability

no data available

12.3Bioaccumulative potential

no data available

12.4Mobility in soil

no data available

12.5Other adverse effects

no data available

SECTION 13: Disposal considerations

13.1Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

14.1UN Number

ADR/RID: UN1299 (For reference only, please check.)

IMDG: UN1299 (For reference only, please check.)

IATA: UN1299 (For reference only, please check.)

14.2UN Proper Shipping Name

ADR/RID: TURPENTINE (For reference only, please check.)

IMDG: TURPENTINE (For reference only, please check.)

IATA: TURPENTINE (For reference only, please check.)

14.3Transport hazard class(es)

ADR/RID: 3 (For reference only, please check.)

IMDG: 3 (For reference only, please check.)

IATA: 3 (For reference only, please check.)

14.4Packing group, if applicable

ADR/RID: III (For reference only, please check.)

IMDG: III (For reference only, please check.)

IATA: III (For reference only, please check.)

14.5Environmental hazards

ADR/RID: Yes

IMDG: Yes

IATA: Yes

14.6Special precautions for user

no data available

14.7Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

15.1Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
Turpentine, oil	Turpentine, oil	8006-64-2	232-350-7
European Inventory of Existing Commercial Chemical Substances (EINECS)			Listed.
EC Inventory			Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Listed.
China Catalog of Hazardous chemicals 2015			Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Listed.
Vietnam National Chemical Inventory			Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Listed.
Korea Existing Chemicals List (KECL)			Listed.

SECTION 16: Other information

Information on revision

Creation Date	July 15, 2019
Revision Date	July 15, 2019

Abbreviations and acronyms

• CAS: Chemical Abstracts Service
• ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
• RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
• IMDG: International Maritime Dangerous Goods
• IATA: International Air Transportation Association
• TWA: Time Weighted Average
• STEL: Short term exposure limit
• LC50: Lethal Concentration 50%
• LD50: Lethal Dose 50%
• EC50: Effective Concentration 50%

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