Titanium(IV) oxide Titania Rutile
According to the UN GHS revision 10
Version: 1.0
Creation Date: July 15, 2019
Revision Date: July 15, 2019
Product name |
Rutile (TiO2) |
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Product number |
- |
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Other names |
Rutile (TiO2); Titanium(IV) oxide; Titanium dioxide |
Identified uses |
Industrial and scientific research use. |
---|---|
Uses advised against |
no data available |
Not classified.
Pictogram(s) | No symbol. |
---|---|
Signal word |
No signal word |
Hazard statement(s) |
none |
Precautionary statement(s) | |
Prevention |
none |
Response |
none |
Storage |
none |
Disposal |
none |
no data available
Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
---|---|---|---|---|
Rutile (TiO2) | Rutile (TiO2) | 1317-80-2 | 215-282-2 | 100% |
If inhaled
Fresh air, rest.
Following skin contact
Rinse and then wash skin with water and soap.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Rinse mouth.
Exposure Routes: inhalation Symptoms: Lung fibrosis; [potential occupational carcinogen] Target Organs: respiratory system (NIOSH, 2016)
Move the affected person from the hazardous exposure. If the exposed person has been overcome, notify someone else and put into effect the established emergency rescue procedures. Do not become a casualty. Understand the facility's emergency rescue procedures and know the locations of rescue equipment before the need arises.
In case of fire in the surroundings, use appropriate extinguishing media.
Literature sources indicate that this chemical is noncombustible. (NTP, 1992)
Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Occupational Exposure limit values
Component | Rutile (TiO2) |
---|---|
CAS No. | 1317-80-2 |
NIOSH considers titanium dioxide to be a potential occupational carcinogen. NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. |
Biological limit values
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Eye/face protection
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Skin protection
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
Thermal hazards
no data available
Physical state |
PHYSICAL DESCRIPTION: Odorless white powder. Tasteless. pH 7.5. Occurs in three crystalline forms. (NTP, 1992) |
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Colour |
White, tetragonal crystals |
Odour |
Odorless |
Melting point/freezing point |
1830-3000°C |
Boiling point or initial boiling point and boiling range |
2500°C |
Flammability |
Noncombustible Solid |
Lower and upper explosion limit/flammability limit |
no data available |
Flash point |
2500-3000°C |
Auto-ignition temperature |
no data available |
Decomposition temperature |
no data available |
pH |
SUSPENSION IN WATER (1 IN 10) IS NEUTRAL TO LITMUS |
Kinematic viscosity |
no data available |
Solubility |
less than 1 mg/mL at 68° F (NTP, 1992) |
Partition coefficient n-octanol/water |
no data available |
Vapour pressure |
0 mm Hg at 68° F Essentially (NTP, 1992) |
Density and/or relative density |
0.06?0.10g/mL |
Relative vapour density |
no data available |
Particle characteristics |
no data available |
5000 mg/cu m; NIOSH considers titanium dioxide to be a potential occupational carcinogen.
no data available
NoncombustibleTITANIUM DIOXIDE is incompatible with strong oxidizers and strong acids. Violent or incandescent reactions may occur with metals (e.g. aluminum, calcium, magnesium, potassium, sodium, zinc and lithium). (NTP, 1992).
no data available
The reaction of lithium and titanium dioxide occurs around 200 deg C with a flash of light; the temperature can reach 900 deg C.
no data available
Acute toxicity
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Cancer in humans: There is inadequate evidence in humans for the carcinogenicity of titanium dioxide. Cancer in experimental animals: There is sufficient evidence in experimental animals for the carcinogenicity of titanium dioxide. Overall evaluation: Titanium dioxide is possibly carcinogenic to humans (Group 2B).
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
no data available
no data available
no data available
no data available
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
ADR/RID: Not dangerous goods. (For reference only, please check.) | IMDG: Not dangerous goods. (For reference only, please check.) | IATA: Not dangerous goods. (For reference only, please check.) |
ADR/RID: No | IMDG: No | IATA: No |
no data available
no data available
Chemical name | Common names and synonyms | CAS number | EC number |
---|---|---|---|
Rutile (TiO2) | Rutile (TiO2) | 1317-80-2 | 215-282-2 |
European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
EC Inventory | Listed. | ||
United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Listed. | ||
Vietnam National Chemical Inventory | Listed. | ||
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
Korea Existing Chemicals List (KECL) | Listed. |
Information on revision
Creation Date | July 15, 2019 |
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Revision Date | July 15, 2019 |
Abbreviations and acronyms
Package&Shipping
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