o-Anisidine o-Anisidine(8CI) 1-Amino-2-methoxybenzene
o-Anisidine Chemical Properties |
Melting point | 3-6 °C(lit.) |
Boiling point | 225 °C(lit.) |
density | 1.092 g/mL at 25 °C(lit.) |
vapor pressure | <0.1 at 25 °C (NIOSH, 1994) |
refractive index | n20/D 1.574(lit.) |
Fp | 210 °F |
storage temp. | Refrigerator |
solubility | 14g/l |
form | Powder/Solid |
pka | 4.52(at 25℃) |
color | Off-white |
PH | 7.3 (1g/l, H2O, 20℃) |
Water Solubility | 13 g/L (20 ºC) |
Sensitive | Light Sensitive |
Merck | 14,667 |
BRN | 386210 |
Henry's Law Constant | 1.25 at 25 °C (approximate - calculated from water solubility and vapor pressure) |
Exposure limits | Potential occupational carcinogen. NIOSH REL: TWA 0.5 mg/m3, IDLH 50 mg/m3; OSHA PEL: TWA 0.5 mg/m3; ACGIH TLV: TWA 0.1 ppm (adopted). |
Dielectric constant | 5.2300000000000004 |
Stability: | Stable. Incompatible with strong oxidizing agents, acid anhydrides, chloroformates, acids, some plastics, rubber. Air sensitive. |
InChIKey | VMPITZXILSNTON-UHFFFAOYSA-N |
LogP | 1.180 |
CAS DataBase Reference | 90-04-0(CAS DataBase Reference) |
NIST Chemistry Reference | Benzenamine, 2-methoxy-(90-04-0) |
IARC | 2A (Vol. Sup 7, 73, 127) |
EPA Substance Registry System | o-Anisidine (90-04-0) |
Safety Information |
Hazard Codes | T,Xi |
Risk Statements | 45-23/24/25-68 |
Safety Statements | 53-45 |
RIDADR | UN 2431 6.1/PG 3 |
OEB | C |
OEL | TWA: 0.5 mg/m3 [skin] |
WGK Germany | 3 |
RTECS | BZ5410000 |
F | 8 |
TSCA | Yes |
HazardClass | 6.1 |
PackingGroup | III |
HS Code | 29222200 |
Hazardous Substances Data | 90-04-0(Hazardous Substances Data) |
Toxicity | Acute oral LD50 for rats 2,000 mg/kg, wild birds 422 mg/kg, mice 1,400 mg/kg, rabbits 870 mg/kg (quoted, RTECS, 1985). |
IDLA | 50 mg/m3 |
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