1,4-Benzenediamine 1,4-Phenylenediamine 4-Phenylenediamine
p-Phenylenediamine Chemical Properties |
Melting point | 138-143 °C (lit.) |
Boiling point | 267 °C (lit.) |
density | 1.135 g/cm3 (20℃) |
vapor density | 3.7 (vs air) |
vapor pressure | 1.08 mm Hg ( 100 °C) |
refractive index | 1.6339 (estimate) |
Fp | 156 °C |
storage temp. | Store below +30°C. |
solubility | Soluble in alcohol, chloroform, ether and hot benzene. |
Colour Index | 76060 |
form | Powder or Flakes |
pka | 4.17(at 25℃) |
color | White, gray, or purple to brown |
PH Range | NonQ uorescence (3.1) to orange/yellow Q uorescence (4.4) |
PH | 9 (50g/l, H2O, 20℃) |
Water Solubility | 47 g/L (25 ºC) |
Merck | 14,7285 |
BRN | 742029 |
Exposure limits | TLV-TWA 0.1 mg/m3 (ACGIH 1989); TWA skin 0.1 mg/m3 (MSHA and OSHA); IDLH 25 mg/m3 (NIOSH); carcinogenicity: Animal Inadequate Evidence (IARC). . |
Stability: | Stable, but oxidizes when exposed to air. Incompatible with oxidizing agents. Store under inert atmosphere. |
Major Application | Nanoparticles, liquid crystal displays, chemical mechanical polishing, bottom antireflective coatings, electrochromic materials, inks, rubber, hair dyes, cosmetics, treatment of virus skin infection |
InChIKey | CBCKQZAAMUWICA-UHFFFAOYSA-N |
LogP | -0.84 at 20℃ |
CAS DataBase Reference | 106-50-3(CAS DataBase Reference) |
IARC | 3 (Vol. 16, Sup 7) 1987 |
NIST Chemistry Reference | 1,4-Benzenediamine(106-50-3) |
EPA Substance Registry System | p-Phenylenediamine (106-50-3) |
Safety Information |
Hazard Codes | T,N,T+,Xn |
Risk Statements | 23/24/25-36-43-50/53-63-36/37/38-45-40-48/22-67-52/53 |
Safety Statements | 28-36/37-45-60-61-28A-24/25-23-53-26 |
RIDADR | UN 1673 6.1/PG 3 |
OEB | D |
OEL | TWA: 0.1 mg/m3 [skin] |
WGK Germany | 3 |
RTECS | SS8050000 |
F | 8-10-23 |
Autoignition Temperature | 567 °C |
TSCA | Yes |
HazardClass | 6.1 |
PackingGroup | III |
HS Code | 29215119 |
Hazardous Substances Data | 106-50-3(Hazardous Substances Data) |
Toxicity | LD50 in rats (mg/kg): 80 orally, 37 i.p. (Burnett) |
IDLA | 25 mg/m3 |
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