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Methacrylicacid methyl ester (6CI,8CI) Methacrylic acid, methyl ester (7CI) 2-(Methoxycarbonyl)-1-propene
Methyl methacrylate Chemical Properties |
Melting point | -48 °C (lit.) |
Boiling point | 100 °C (lit.) |
density | 0.936 g/mL at 25 °C (lit.) |
vapor density | 3.5 (vs air) |
vapor pressure | 29 mm Hg ( 20 °C) |
FEMA | 4002 | METHYL 2-METHYL-2-PROPENOATE |
refractive index | n20/D 1.414(lit.) |
Fp | 50 °F |
storage temp. | 2-8°C |
solubility | 15g/l |
form | Crystalline Powder or Crystals |
color | White to pale yellow |
Odor | at 0.10 % in dipropylene glycol. acrylic aromatic fruity |
Odor Type | acrylate |
explosive limit | 2.1-12.5%(V) |
Odor Threshold | 0.21ppm |
Water Solubility | 15.9 g/L (20 ºC) |
Merck | 14,5941 |
JECFA Number | 1834 |
BRN | 605459 |
Henry's Law Constant | 2.46 x 10-4 atm?m3/mol at 20 °C (approximate - calculated from water solubility and vapor pressure) |
Exposure limits | NIOSH REL: TWA 100 ppm (410 mg/m3), IDLH 1,000 ppm; OSHA PEL: TWA 100 ppm; ACGIH TLV: TWA 100 ppm with intended TWA and STEL values of 50 and 100 ppm, respectively. |
Dielectric constant | 2.9(20℃) |
Stability: | Volatile |
InChIKey | VVQNEPGJFQJSBK-UHFFFAOYSA-N |
LogP | 1.38 at 20℃ |
CAS DataBase Reference | 80-62-6(CAS DataBase Reference) |
IARC | 3 (Vol. Sup 7, 60) 1994 |
NIST Chemistry Reference | 2-Propenoic acid, 2-methyl-, methyl ester(80-62-6) |
EPA Substance Registry System | Methyl methacrylate (80-62-6) |
Safety Information |
Hazard Codes | F,Xi,T |
Risk Statements | 11-37/38-43-39/23/24/25-23/24/25 |
Safety Statements | 24-37-46-45-36/37-16-7 |
RIDADR | UN 1247 3/PG 2 |
OEB | A |
OEL | TWA: 100 ppm (410 mg/m3) |
WGK Germany | 1 |
RTECS | OZ5075000 |
Autoignition Temperature | 815 °F |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | II |
HS Code | 29161410 |
Hazardous Substances Data | 80-62-6(Hazardous Substances Data) |
Toxicity | The acute toxicity of methyl methacrylate is low. Irritation of the skin, eye, and nasal cavity has been observed in rodents and rabbits exposed to relatively high concentrations of methyl methacrylate. The chemical is a mild skin sensitizer in animals. The effect observed most frequently at lowest concentration after repeated inhalation exposure to methyl methacrylate is irritation of the nasal cavity. Effects on the kidney and liver at higher concentrations have also been reported. |
IDLA | 1,000 ppm |
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