1,4-Dioxane

1,4-Dioxane

1,4-Dioxane

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1 Metric Ton

Negotiable

  • Min.Order :1 Metric Ton
  • Purity: 98.0% Min
  • Payment Terms : L/C,D/A,D/P,T/T,,MoneyGram

Keywords

123-91-1 1,4-Dioxane C4H8O2

Quick Details

  • Appearance:colourless liquid
  • Application:For Organic synthsis
  • PackAge:As your request
  • ProductionCapacity:10|Metric Ton|Day
  • Storage:Room temperature
  • Transportation:AS PER MSDS

Details:

 
1,4-Dioxane Chemical Properties
mp  12 °C
bp  101 °C
density  1.500 g/mL at 25 °C
vapor density  3 (vs air)
vapor pressure  27 mm Hg ( 20 °C)
refractive index  n20/D 1.422(lit.)
Fp  54 °F
storage temp.  Flammables area
Water Solubility  SOLUBLE
Sensitive  Hygroscopic
Merck  14,3300
BRN  102551
Stability: Stable. Incompatible with oxidizing agents, oxygen, halogens, reducing agents, moisture. Highly flammable - note wide explosive range. May form explosive peroxides in storage (rate of formation increased by heating, evaporation or exposure to light).
CAS DataBase Reference 123-91-1(CAS DataBase Reference)
NIST Chemistry Reference 1,4-Dioxane(123-91-1)
EPA Substance Registry System 1,4-Dioxane(123-91-1)
 
Safety Information
Hazard Codes  Xn,F,T
Risk Statements  45-46-11-36/38-48/23/24/25-65-66-40-36/37-19-41-37/38-39/23/24/25-23/24/25-48/20/22-38-22-36/37/38-10
Safety Statements  9-16-36/37-46-45-53-7-62-26-24/25-23-S9-S46-S36/37-S16
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  JG8225000
8
HazardClass  3
PackingGroup  II
Hazardous Substances Data 123-91-1(Hazardous Substances Data)
MSDS Information
Provider Language
SigmaAldrich English
ACROS English
ALFA English
 
1,4-Dioxane Usage And Synthesis
Chemical Properties colourless liquid
Usage Suitable for HPLC, spectrophotometry, environmental testing
General Description A clear colorless liquid with a faint ethereal odor. Flash point 55°F. Slightly denser than water and soluble in water. Vapors heavier than air. Susceptible to autooxidation to form peroxides.
Air & Water Reactions Highly flammable. When exposed to air 1,4-Dioxane undergoes autooxidation with formation of peroxides. In the distillation process peroxides will concentrate causing violent explosion. Water soluble.
Reactivity Profile 1,4-Dioxane is a flammable liquid; when exposed to air 1,4-Dioxane undergoes autooxidation with formation of peroxides. In the distillation process peroxides will concentrate causing violent explosion. The addition complex with sulfur trioxide (1:1) sometimes decomposes violently on storing at room temperature [Sisler, H. H. et al., Inorg. Synth., 1947, 2, p. 174]. Evaporation of boron trifluoride in aqueous 1,4-Dioxane with nitric acid led to an explosion upon addition of perchloric acid [MCA Guide, 1972, p. 312]. Explosive reaction with Raney nickel catalyst above 210° C {Mozingo R., Org. Synth., 1955, Coll. Vol. 3, p. 182].
Health Hazard No significant irritation from brief exposure of skin; prolonged or repeated exposure may cause a rash or burn and absorption of toxic amounts leading to serious injury of liver and kidney. Chemical has poor warning properties; illness may be delayed. Moderately irritating to eyes; overexposure may cause corneal injury.

 

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