Malononitrile

Malononitrile

Malononitrile

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1 Kilogram

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  • Min.Order :1 Kilogram
  • Purity: 99.0%Min
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Keywords

Malononitrile 109-77-3 C3H2N2

Quick Details

  • Appearance:conform
  • Application:For pharmacy
  • PackAge:according to the demand of cusotmer
  • ProductionCapacity:1|Metric Ton|Day
  • Storage:Room Temperature
  • Transportation:shipped

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Details:

Malononitrile Basic information
Product Name: Malononitrile
Synonyms: AKOS BBS-00004370;METHYLENE DICYANIDE;METHYLENE CYANIDE;MALONODINITRILE;MALONITRILE;MALONONITRILE;MALONIC ACID DINITRILE;MDN
CAS: 109-77-3
MF: C3H2N2
MW: 66.06
EINECS: 203-703-2
Product Categories: Dinitriles;Dinitriles & Trinitriles;Agrochemicals;Pharmaceutical intermediates
Mol File: 109-77-3.mol
Malononitrile Structure
 
Malononitrile Chemical Properties
mp  30-32 °C(lit.)
bp  220 °C(lit.)
density  1.049 g/mL at 25 °C(lit.)
refractive index  1.4150
Fp  234 °F
storage temp.  2-8°C
Water Solubility  13.3 g/100 mL (20 ºC)
Merck  14,5711
BRN  773697
CAS DataBase Reference 109-77-3(CAS DataBase Reference)
NIST Chemistry Reference Malononitrile(109-77-3)
EPA Substance Registry System Propanedinitrile(109-77-3)
 
Safety Information
Hazard Codes  T,N
Risk Statements  23/24/25-50/53
Safety Statements  23-27-45-60-61
RIDADR  UN 2647 6.1/PG 2
WGK Germany  3
RTECS  OO3150000
8
HazardClass  6.1
PackingGroup  II
Hazardous Substances Data 109-77-3(Hazardous Substances Data)
MSDS Information
Provider Language
SigmaAldrich English
ACROS English
ALFA English
 
Malononitrile Usage And Synthesis
Chemical Properties Solidified melt
Usage Malononitrile is an important building block for the syntheses of pharmaceuticals (e.g. triamterene, adenine and methotrexate), thiamin (vitamin B1), pesticides dyestuffs for color photography and synthetic fibers (e.g. vinylidene cyanide). Product Data Sheet
Usage Malononitrile is an important building block for the syntheses of pharmaceuticals (e.g. triamterene, adenine and methotrexate), thiamine, pesticides, special dyestuffs for color photography and synthetic fibres. Product Data Sheet
Usage The chemical properties of malononitrile are determined by the nucleophilicity of the malononitrile anion, formed by deprotonation with relatively weak bases and by the two electrophilic cyano groups.
General Description A white-colored crystalline solid. Denser than water and soluble in water. Toxic by ingestion and may severely irritate skin and eyes. May polymerize violently if exposed to temperatures above 266°F. Used to make other chemicals.
Air & Water Reactions Soluble in water.
Reactivity Profile Malononitrile is a white, low-melting powder (m. p. 30.5° C), toxic, combustible. Violent polymerization on contact with strong bases (sodium hydroxide, potassium hydroxide) or when heated above 130° C. When stored at 70-80° C for 2 months, spontaneous explosion (decomposition) occurred [Bretherick, 5th ed., 1995, p. 394].
Health Hazard Metabolized by body to cyanide and thiocyanate; effects of inhalation of toxic fumes will be related to cyanide. Causes brain and heart damage related to lack of cellular oxygen. It is classified as extremely toxic. Probable oral lethal dose for humans is 5-50 mg/kg, or between 7 drops and 1 teaspoonful, for a 70 kg (150 lb.) person.
Fire Hazard When heated to decomposition, Malononitrile emits highly toxic fumes (cyanide). May polymerize violently on prolonged heating. Avoid heat. Hazardous polymerization may occur, at prolonged heating at 266F or contact with strong bases at lower temperatures.
 
Malononitrile Preparation Products And Raw materials
Raw materials Phosphorus oxychloride-->Sodium chloride-->Ethyl cyanoacetate-->Dichloroethane-->2-Cyanoacetamide-->Dehydrolyzing agent-->Allene
Preparation Products 5-AMINO-4-ISOXAZOLECARBONITRILE-->5-(AMINOMETHYL)PYRIMIDIN-4-AMINE-->1,4,5,8-Naphthalenetetracarboxylic acid-->2-AMINO-3-CYANO-4-CHLORO-5-FORMYLTHIOPHENE-->3-CYANO-7-ETHOXYCOUMARIN-->4-AMINOPYRIMIDINE-5-CARBOXAMIDE-->2-AMINO-5,6-DIHYDRO-4H-CYCLOPENTA[B]THIOPHENE-3-CARBOXAMIDE-->5-AMINO-1-(4-CHLOROPHENYL)-1H-PYRAZOLE-4-CARBONITRILE-->2,4,6-Triaminopyrimidine-->3-CYANO-7-METHOXYCOUMARIN-->Azimsulfuron-->4,6-DIAMINO-2-METHYLMERCAPTOPYRIMIDINE-->5-AMINO-4-CYANO-3-METHYL-THIOPHENE-2-CARBOXYLIC ACID ETHYL ESTER-->2-Amino-3-cyanopyridine-->2-AMINO-6-METHYL-4,5,6,7-TETRAHYDRO-1-BENZOTHIOPHENE-3-CARBONITRILE-->2-AMINO-3,5-DICYANOPYRIDINE-->2,4-DIAMINOPYRIMIDINE-5-CARBOXYLIC ACID-->2-AMINO-5,6-DIHYDRO-4H-CYCLOPENTA[B]THIOPHENE-3-CARBONITRILE-->2-AMINO-4,5-DIMETHYL-THIOPHENE-3-CARBONITRILE-->4-Amino-6-methylpyrimidine-5-carbonitrile ,97%-->2-AMINO-3-CYANO-4-METHYL-5-CARBMETHOXY THIOPHENE-->2,4-DIAMINOPYRIMIDINE-5-CARBONITRILE-->2-AMINO-4,5,6,7-TETRAHYDRO-1-BENZOTHIOPHENE-3-CARBONITRILE-->2-Aminonicotinic acid-->Levosimendan-->4-AMINO-1,2,5-OXADIAZOLE-3-CARBONITRILE-->2-AMINO-6-METHYL-4,5,6,7-TETRAHYDROTHIENO[2,3-C]PYRIDINE-3-CARBONITRILE-->5-AMINO-1-PHENYLPYRAZOLE-4-CARBONITRILE-->2-AMINO-4-METHYL-QUINOLINE-3-CARBONITRILE-->[2-[4-(dihexylamino)-2-methylbenzylidene]benzo[b]thien-3(2H)-ylidene]malononitrile S,S-dioxide -->4,6-Dimethyl-2-hydroxypyridine-->2,4,6-TRIAMINO-5-NITROPYRIMIDINE-->4,6-DIAMINO-2-MERCAPTOPYRIMIDINE-->3,5-Difluorophenylacetic acid-->4-AMINOPYRIMIDINE-5-CARBONITRILE-->4-AMINO-2-(METHYLTHIO)PYRIMIDINE-5-CARBONITRILE-->2-AMINO-6-CHLORO-3,5-DICYANOPYRIDINE-->Solvent Red 197-->2-OXO-6-PHENYL-4-(TRIFLUOROMETHYL)-1,2-DIHYDRO-3-PYRIDINECARBONITRILE

 

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