Allethrin 584-79-2

Details:

Product Name: Allethrin
Synonyms: (.+/-.)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl 2,2-dimethyl-3-(2-methylprop-1-enyl) cyclopropylcarboxylate;(.+/-.)-Allelrethonyl (.+/-.)-cis,trans-chrysanthemate;(+)-allelrethonyl(+)-cis,trans-chrysanthemate;(+)-trans-Bioallethrin;(+)-trans-Chrysanthemumic acid ester of (.+/-.)-allethrolone;(1rs)-3-allyl-2-methyl-4-oxocyclopent-2-enyl-(1r)-trans-chrysanthemate;(1rs)-cis,trans-chrysanthemate;(rs)-3-allyl-2-methyl-4-oxocyclopent-2-enyl
CAS: 584-79-2
MF: C19H26O3
MW: 302.41
EINECS: 209-542-4
Product Categories: INSECTICIDE;HERBICIDE;Endocrine Disruptors (Draft)Fluorescent Probes, Labels, Particles and Stains;Other Fluorescent LabelsPesticides;A;AA to ALMethod Specific;Alphabetic;EPA;Fluorescent Labels;A-BAlphabetic;Alpha sort;B;BI - BZPesticides;Insecticides;Pesticides&Metabolites;Pyrethroids;NULL
Mol File: 584-79-2.mol
Allethrin Structure
Allethrin Chemical Properties
bp  160°C
density  1.01
Fp  66 °C
storage temp.  0-6°C
CAS DataBase Reference 584-79-2(CAS DataBase Reference)
NIST Chemistry Reference Bioallethrin(584-79-2)
EPA Substance Registry System Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1- propenyl)-, 2-methyl-4-oxo-3-(2-propenyl)- 2-cyclopenten-1-yl ester(584-79-2)
Safety Information
Hazard Codes  Xn;N,N,Xn
Risk Statements  20/22-50/53-40
Safety Statements  36-60-61-36/37-24/25-23
RIDADR  UN 3082
RTECS  GZ1925000
HazardClass  6.1(b)
PackingGroup  III
MSDS Information
Provider Language
Allethrin English
Allethrin Usage And Synthesis
Chemical Properties Yellow Oil
Usage Allethrin is a synthetic pyrethroid derivative used as an insecticide. Allethrin is commonly used in many household insecticide products due to its low toxicity towards humans.
General Description A clear amber-colored viscous liquid. Insoluble and denser than water. Toxic by ingestion, inhalation, and skin absorption. A synthetic household insecticide that kills flies, mosquitoes, garden insects, etc.
Air & Water Reactions Insoluble in water.
Reactivity Profile Allethrin is an ester and ketone. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Health Hazard Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.
Allethrin Preparation Products And Raw materials
Raw materials Chloral-->Cyclopentanone-->2-Methylfuran-->Ethyl chrysanthemumate-->3-Furaldehyde-->Chrysanthemoyl chloride-->TRANS-(+)-CHRYSANTHEMIC ACID-->rich_d_transallethrin-->Conversion catalyst-->D-trans-Allethrin