100-39-0 C7H7Br Benzyl bromide
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Benzyl bromide Basic information |
Product Name: | Benzyl bromide |
Synonyms: | (bromomethyl)-benzen;1-Bromotoluene;ai3-15300;alpha-bromo-toluen;Bromophenylmethane;-Bromotoluene;Bromotoluene, alpha;bromotoluene,alpha |
CAS: | 100-39-0 |
MF: | C7H7Br |
MW: | 171.03 |
EINECS: | 202-847-3 |
Product Categories: | Pharmaceutical Intermediates;Aromatic Halides (substituted);Organics;Benzyl;Biochemistry;Reagents for Oligosaccharide Synthesis;Aryl;Building Blocks;C7;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks |
Mol File: | 100-39-0.mol |
Benzyl bromide Chemical Properties |
mp | -3 °C |
bp | 198-199 °C(lit.) |
density | 1.44 g/mL at 20 °C |
vapor density | 5.8 (vs air) |
refractive index |
n |
Fp | 188 °F |
storage temp. | Store at RT. |
Sensitive | Moisture Sensitive/Light Sensitive |
Merck | 14,1128 |
BRN | 385801 |
Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 100-39-0(CAS DataBase Reference) |
NIST Chemistry Reference | Benzene, (bromomethyl)-(100-39-0) |
EPA Substance Registry System | Benzene, (bromomethyl)-(100-39-0) |
Safety Information |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 39-2 |
RIDADR | UN 1737 6.1/PG 2 |
WGK Germany | 2 |
RTECS | XS7965000 |
F | 9-19-21 |
HazardClass | 6.1 |
PackingGroup | II |
Hazardous Substances Data | 100-39-0(Hazardous Substances Data) |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ACROS | English |
ALFA | English |
Benzyl bromide Usage And Synthesis |
Chemical Properties | Clear light amber liquid |
General Description | A colorless liquid with an agreeable odor. Toxic by inhalation and by skin absorption. Benzyl bromide is slightly soluble in water and denser than water (density 1.44 g / cm3 (Aldrich)). A lachrymator. Corrosive to metals and tissue. |
Air & Water Reactions | Sensitive to exposure to light and moisture. Slightly soluble in water. |
Reactivity Profile | Benzyl bromide reacts with water, alcohols, common metals (except nickel and lead), bases, amines and oxidizing agents. . Benzyl bromide stored over activated 4A molecular sieve burst a bottle due to condensation-polymerization reaction with generation of HBr gas, [Chem. Eng. News, 1979, 57(12), 74]. |
Health Hazard | Inhalation causes irritation of nose and throat; severe exposure may cause pulmonary edema. Vapors cause severe eye irritation; liquid can burn eyes. Skin contact causes irritation. Ingestion causes irritation of mouth and stomach. |
Benzyl bromide Preparation Products And Raw materials |
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