7718-98-1 VANADIUM(III) CHLORIDE Cl3V
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VANADIUM(III) CHLORIDE Basic information |
Product Name: | VANADIUM(III) CHLORIDE |
Synonyms: | VANADIUM CHLORIDE;Vanadium(Ⅲ)chloride;VANADIUM(III) CHLORIDE;VANADIUM TRICHLORIDE;Vanadium chloride (VCl3);vanadiumchloride(vcl3);VCl3;Vanadiumchlorideanhydrous |
CAS: | 7718-98-1 |
MF: | Cl3V |
MW: | 157.3 |
EINECS: | 231-744-6 |
Product Categories: | Vanadium Salts;Alternative Energy;Catalysis and Inorganic Chemistry;CatalystsChemical Synthesis;Materials for Hydrogen Storage;Salts;VanadiumMetal and Ceramic Science;metal halide;Alternative Energy;Catalysis and Inorganic Chemistry;Catalysts;Chemical Synthesis;Materials for Hydrogen Storage;Materials Science;Metal and Ceramic Science;Vanadium;Vanadium Salts |
Mol File: | 7718-98-1.mol |
VANADIUM(III) CHLORIDE Chemical Properties |
mp | 250 °C |
density | 3 g/mL at 25 °C(lit.) |
storage temp. | water-free area |
Sensitive | Moisture Sensitive |
CAS DataBase Reference | 7718-98-1(CAS DataBase Reference) |
Safety Information |
Hazard Codes | C |
Risk Statements | 22-34 |
Safety Statements | 26-27-28-36/39-45 |
RIDADR | UN 2475 8/PG 3 |
WGK Germany | 3 |
RTECS | YW2800000 |
F | 3-10 |
HazardClass | 8 |
PackingGroup | III |
MSDS Information |
Provider | Language |
---|---|
SigmaAldrich | English |
ACROS | English |
ALFA | English |
VANADIUM(III) CHLORIDE Usage And Synthesis |
Chemical Properties | dark blue to violet to black powder |
General Description | A pink crystalline solid. Density 3.00 g / cm3. Irritates skin and eyes. Used to make other chemicals. |
Air & Water Reactions | Deliquescent. Generates acid mists when exposed to moist air. Dissolves in water with formation of an acidic solution and generation of acidic fumes. |
Reactivity Profile | VANADIUM(III) CHLORIDE attacks many organic compounds. Can catalyze organic reactions. Aqueous solutions react as acids to neutralize bases. These neutralizations generate heat, but less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. Combination of the trichloride with methylmagnesium iodide, or other Grignard type reagents, can be violently explosive under a variety of conditions, Chem. Rev., 1955, 55, 560. |
Health Hazard | TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. |
Fire Hazard | Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. |
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