Pyridine, for spect...

Pyridine, for spectroscopy, 99+%

Pyridine, for spectroscopy, 99+%

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1 Metric Ton

Negotiable

Min.Order :1 Metric Ton
Purity: 99%
Payment Terms : L/C,D/A,D/P,T/T,,MoneyGram

Keywords

110-86-1 Pyridine, for spectroscopy, 99+% C5H5N

Quick Details

Appearance:Colorless to light yellow liquid
Application:Reagent
PackAge:as per buyers
ProductionCapacity:10|Metric Ton|Day
Storage:R.T.
Transportation:as per msds

Superiority:

Good quantity

Azabenzene Basic information

Product Name:	Azabenzene
Synonyms:	ai3-01240;Azine;cp32;NCI-C55301;Piridina;Pirydyna;Pyridin(1.Modifikation);pyridinecarboxylicacid,2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1h-imidazol-2-yl)-5-methyl
CAS:	110-86-1
MF:	C5H5N
MW:	79.1
EINECS:	203-809-9
Product Categories:	Pyridine;Organohalides;Boronic ester;Organoborons;Halogenated;Fluorinated;Building Blocks;Boronic acid;Carboxy;Alkoxy;Organosilane;Organostannes;Tributylstanny;Chemistry;Alphabetic;P;PU - PZ;CHROMASOLV PlusCHROMASOLV Solvents (HPLC, LC-MS);CHROMASOLV(R) Plus;LC-MS Plus and Gradient;Amber Glass Bottles;ReagentPlus(R) Solvent Grade Products;ReagentPlus(R)Solvents;ACS Grade Solvents;ACS GradeSemi-Bulk Solvents;ACS GradeSolvents;Carbon Steel Cans with NPT Threads;Returnable Container Solvents;Biotech SolventsSolvents;Solvent Bottles;Solvents;Sure/Seal Bottles;P-S;Alpha Sort;Volatiles/ Semivolatiles;Aluminum Bottles;O-P, Puriss p.a. ACS;Puriss p.a. ACS;Analytical Reagents for General Use;O-P, Puriss p.a.;Puriss p.a.;Alphabetical Listings;Flavors and Fragrances;O-P;Spectrophotometric Grade Solvents;Spectrophotometric GradeSolvents;PVC Coated Bottles;ReagentPlus(R) Solvent Grade ProductsSolvents;Anhydrous Grade SolventsSolvents;AnhydrousSolvents;Amber Glass Bottles;NMR;Solvent Bottles;Solvent by Application;Solvent by Type;Solvent Packaging Options;Spectrophotometric Grade;Spectrophotometric Solvents;Spectroscopy Solvents (IR;UV/Vis);ACS and Reagent Grade Solvents;ReagentPlus;ReagentPlus Solvent Grade Products;Biotech Solvents;Sure/Seal Bottles;ACS Grade;Analytical Reagents;Analytical Reagents for General Use;Analytical/Chromatography;Multi-Compendial;Puriss p.a.;Puriss p.a. ACS;PVC Coated Bottles;Aluminum Bottles;CHROMASOLV Plus;Chromatography Reagents &;HPLC &;HPLC Plus Grade Solvents (CHROMASOLV);HPLC/UHPLC Solvents (CHROMASOLV);UHPLC Solvents (CHROMASOLV);ACS Grade Solvents;Carbon Steel Cans with NPT Threads;Semi-Bulk Solvents
Mol File:	110-86-1.mol

Details:

Azabenzene Chemical Properties

mp	-42 °C
bp	96-98 °C(lit.)
density	0.983 g/mL at 20 °C
vapor density	2.72 (vs air)
vapor pressure	23.8 mm Hg ( 25 °C)
refractive index	n20/D 1.509(lit.)
FEMA	2966
Fp	68 °F
storage temp.	Store at RT.
Water Solubility	Miscible
FreezingPoint	-42℃
Merck	14,7970
BRN	103233
Stability:	Stable. Flammable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference	110-86-1(CAS DataBase Reference)
NIST Chemistry Reference	Pyridine(110-86-1)
EPA Substance Registry System	Pyridine(110-86-1)

Safety Information

Hazard Codes	T,N,F,Xn
Risk Statements	11-20/21/22-39/23/24/25-23/24/25-52-36/38
Safety Statements	36/37/39-38-45-61-28A-26-28-24/25-22-36/37-16-7
RIDADR	UN 1282 3/PG 2
WGK Germany	2
RTECS	UR8400000
F	3-10
Hazard Note	Highly Flammable/Harmful
HazardClass	3
PackingGroup	II
Hazardous Substances Data	110-86-1(Hazardous Substances Data)

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

Azabenzene Usage And Synthesis

Chemical Properties	Colorless to light yellow liquid
General Description	A clear colorless to light yellow liquid with a penetrating nauseating odor. Density 0.978 g / cm3. Flash point 68°F. Vapors are heavier than air. Toxic by ingestion and inhalation. Combustion produces toxic oxides of nitrogen.
Air & Water Reactions	Highly flammable. Soluble in water.
Reactivity Profile	Azabenzene is a base. Reacts exothermically with acids. During preparation of a complex of Azabenzene with chromium trioxide, an acid, the proportion of chromium trioxide was increased. Heating from this acid-base reaction led to an explosion and fire [MCA Case History 1284 1967]. A 0.1% solution of Azabenzene (or other tertiary amine) in maleic anhydride at 185°C gives an exothermic decomposition with rapid evolution of gas [Chem Eng. News 42(8); 41 1964]. Mixing Azabenzene in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, nitric acid (70%), oleum, sulfuric acid (96%), or propiolactone [NFPA 1991]. The combination of iodine, Azabenzene, sulfur trioxide, and formamide developed a gas over pressurization after several months. This arose from the slow formation of sulfuric acid from external water, or from dehydration of the formamide to hydrogen cyanide. Ethylene oxide and SO2 can react violently in Azabenzene solution with pressurization if ethylene oxide is in excess (Nolan, 1983, Case History 51).
Health Hazard	Vapor irritates eyes and nose. Liquid irritates skin and is absorbed through the skin. Overexposure causes nausea, headache, nervous symptoms, increased urinary frequency.
Fire Hazard	Behavior in Fire: Vapor is heavier than air and may travel considerable distance to source of ignition and flash back.

Azabenzene Preparation Products And Raw materials

Preparation Products

Methyl 2-Fluoroisonicotinate-->2-ACETYL-5-CYANOTHIOPHENE-->5-BROMO-2-FLUOROCINNAMIC ACID-->4-NITROISOPHTHALIC ACID-->3,5-DIMETHOXYCINNAMIC ACID-->2-(2-Butoxyethoxy)ethyl acetate-->2,4-MESITYLENEDISULFONYL DICHLORIDE-->(4-FLUORO-BENZYL)-METHYL-AMINE-->1-Phenacylpyridinium bromide-->3-(TRIFLUOROMETHOXY)CINNAMIC ACID-->trans-Ferulic acid-->3-(Trifluoromethyl)pyrazole-->4-Fluorocinnamic acid-->Indigosol Green Blue IBC-->2-Amino-4-methyl-5-acetylthiazole-->Benzyl 2-chloroacetate-->5-ACETAMIDONICOTINIC ACID-->7-ACETOXYCOUMARIN-->2-AMINO-4-METHYL-QUINOLINE-3-CARBONITRILE-->N-PHENYLISONICOTINAMIDE-->Allyl methyl carbonate-->PYRIDINE-3-SULFONYL CHLORIDE-->3,5-Dimethoxy-4-hydroxybenzaldehyde-->2,4,5,6-TETRAMETHYLBENZENEDISULFONYL DICHLORIDE-->3-(3-METHYL-2-THIENYL)ACRYLIC ACID-->Vat Grey M-->17beta-Hydroxy-17-methylandrosta-4,9(11)-dien-3-one-->butyl N-phenylcarbamate-->3-Methoxycinnamic acid-->1-CHLORO-2-METHYLPROPYL CHLOROFORMATE-->Pyrazinecarbonitrile-->2-AMINO-6-CHLORO-3,5-DICYANOPYRIDINE-->4-BROMO-TETRAHYDROPYRAN-->Phenylcarbamic acid propyl ester-->Hydrocortisone acetate-->5-METHYLPICOLINIC ACID-->4-Acetamido-2-chloropyridine-->Pyridinium toluene-4-sulphonate-->1,2,4-Triazolo[4,3-a]pyridin-3(2H)-one-->Paraquat dichloride

Raw materials

Sulfuric acid -->Ammonia-->Benzene-->COAL TAR-->3-Picoline-->COKEOVENGAS-->1,5-DIAMINOPENTANE DIHYDROCHLORIDE

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