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23220-52-2 meso-2,3-Diaminosuccinic acid MESO-2 3-DIAMINOSUCCINIC ACID
Product Name: MESO-2 3-DIAMINOSUCCINIC ACID
Synonyms: erythro-3-aminoaspartic acid;(2R,3S)-diaminosuccinic acid;(2R,3S)-2,3-Diaminosuccinic acid;(3R)-3-Amino-L-aspartic acid;Einecs 245-500-1
CAS: 23220-52-2
MF: C4H8N2O4
MW: 148.11732
EINECS: 245-500-1
Product Categories: Others;Peptide Synthesis;Unnatural Amino Acid Derivatives;amino
Mol File: 23220-52-2.mol
MESO-2 3-DIAMINOSUCCINIC ACID Structure
MESO-2 3-DIAMINOSUCCINIC ACID Chemical Properties
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
MESO-2 3-DIAMINOSUCCINIC ACID Usage And Synthesis
Purification Methods Crystallise the acid from water. Also, dissolve it in dilute NaOH and add AcOH to pH 5-6 and allow it to crystallise (m 304o dec). Alternatively dissolve the acid in aqueous NH3 and boil; when the NH3 has evaporated, the acid separates, filter it off and dry it at room temperature in a vacuum. In another procedure 1g of acid is dissolved in 10mL of conc HCl + 15mL of H2O at 80o, filter immediately, dilute with 20mL of H2O and allow to stand for 24hours. When the monohydrochloride (0.7g, m 175-156o dec) crystallises out, filter and dry it. It has also been purified by dissolving it in the minimum volume of 10% HCl, filtering, and diluting with 5volumes of H2O when the crystals separate slowly on standing. The acid is filtered off after 24hours and dried (m 306-306o dec). Similar procedures were used for the dl-isomer. [Kenner J Org Chem 13 28 1948, McKennis & Yard J Org Chem 23 980 1958, Beilstein 4 III 1528, 4 IV 3025.]
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