Add time:07/20/2019         Source:sciencedirect.com

Spectroscopic steady state studies of four monosubstituted derivatives of methyl benzoate dissolved in methylcyclohexane (McH), tetrahydrofuran (THF), ethanol (EtOH) and isopentane–diethyl ether mixture (IP–DE) have been performed at 293 and 77 K. The determined electronic energy values and oscillator strengths are compared with those obtained from quantum chemical calculations. Good agreement between experimental and theoretical energy values is noted. The average ΔEi=|Eiexp-Eith| value is smaller than 5 percent. A reasonable agreement is noted between intensities of separated bands and oscillator strength of corresponding transitions. The relative ratio of fluorescence to phosphorescence intensity Ifl/Iph of ortho-substituted compounds dissolved in non-polar, polar and protic solvents is higher than that of the para-substituted derivatives of methyl benzoate. The spectroscopic studies show that methyl ortho-hydroxy benzoate in the excited state S1 forms H-bonded dimers in the solvents used. At 77 K the dimer fluorescence dominates the phosphorescence emission. The long wavelength absorption band (C) of amino-substituted methyl benzoates consists of two transitions in agreement with our theoretical calculations and a suggestion made by Shabestary and El-Bayoumi [N. Shabestary, M.A. El-Bayoumi, Chem. Phys. Lett. 106 (1984) 107].

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