Fluoride ion mediated conjugate addition reactions of 1-acyloxy-2-propenyltrimethylsilane. Synthesis of 3-(1-acyloxy-2-propenyl)alkanones.-Science-Chemical Encyclopedia-lookchem

Fluoride ion mediated conjugate addition reactions of 1-acyloxy-2-PROPENYLTRIMETHYLSILANE (cas 18163-07-0). Synthesis of 3-(1-acyloxy-2-propenyl)alkanones.
Add time:07/21/2019 Source:sciencedirect.com

The reaction of 1-acyloxy-2-propenyltrimethylsilane (1) with α, β-unsaturated ketones in the presence of tetra-n-butylammonium fluoride has been investigated. In all cases the reaction was regiospecific resulting in the conjugate addition of a 1-acyloxy-2-propenyl function.

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