Add time:07/19/2019         Source:sciencedirect.com

Two pyridoxal containing Schiff bases obtained by condensation of pyridoxal hydrochloride with N,N-dimethylethylenediamine (HL1) and N,N-diethylethylenediamine (HL2) are used for the syntheses of three new copper (II) complexes [Cu(HL1)(H2O)Cl]Cl (1), [Cu(L1)Cl] (2) and [Cu(L2)Cl] (3). The single crystal X-ray structures of all the three copper(II) complexes are determined. Redox potentials for the mononuclear complexes are measured by cyclic voltammetry experiments. The DFT and TDDFT results have been used to interpret the experimental properties.

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