Add time:07/19/2019         Source:sciencedirect.com

The stereochemistry of the methoxymercuration of 1-cyano-3-cyclohexene and trans-1,2-dicyano-4-cyclohexene has been studied by NMR spectroscopy using partially deuterated model compounds. The configuration of the methoxymercurials formed suggest that the previously postulated “specific directing should be discounted.

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