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  • Catalysis of CC-coupling reactions by cyclopropenylidene (cas 16165-40-5) palladium complexes
  • Add time:07/29/2019         Source:sciencedirect.com

    Several mixed palladium(II) complexes bearing 2,3-diarylcyclopropenylidene (cas 16165-40-5) ligands (aryl = phenyl, mesityl, naphthyl) and triaryl- and trialkylphosphines have been prepared. Single crystal structure details of one of the dimeric chloro-bridged complexes as well as of two monomeric phosphine substituted complexes are presented and compared with appropriate structural features of similar 2,3-diaminocyclopropenylidene- and cycloheptatrienylidene complexes. The new complexes were tested as catalysts in Suzuki–Mijaura coupling reactions with bromo- and chloroarenes and their catalytic activity compared with that of analogous NHC- and cycloheptatrienylidene complexes.

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