Add time:07/20/2019         Source:sciencedirect.com

The HCo(CO)4-catalyzed isomerization of PhCD2CHCH2 carried out in the presence of an excess of p-allyltoluene gave principally trans-PhCDCHCH3. This result rules out a catalyzed [1,3] sigmatropic shift but is consistent with a 1,2-addition-elimination mechanism.

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