Add time:07/23/2019         Source:sciencedirect.com

Synthetic strategy of functional group transformation has been utilized to modify the acidic hydroxyl (−OH) of a series of pyridone based heterocyclic dyes into basic secondary amine (−NHCH2CH2CH2OCH3), so as to improve the color instability of hydrazone dyes under the basic condition. Namely, five pairs of 6-(3-methoxypropylamino)pyridin-2-one based azo dyes have been synthesized showing significantly increased pH stability, which can be verified by corresponding UV–Vis spectra. Successful configuration transformation from the NHN= unit in the hydrazone dyes into the NN− one in the resultant azo dyes is believed to obstruct the proton transfer between the pyridone and azo/hydrazone units (azo-hydrazone tautomerism), thereby enhancing the pH stability especially under the alkaline condition. In addition, different N-substituted groups at the pyridone ring and push-pull electronic substituted groups at the phenyl ring have been selected to make spectral and structural comparisons before and after the functional group transformation.

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