Add time:07/22/2019         Source:sciencedirect.com

The ether-soluble resin glycoside (‘jalapin’) fraction obtained from scammony roots, on alkaline hydrolysis, gave a glycosidic acid, scammonic acid A, together with isobutyric, 2S-methylbutyric and tiglic acids. In addition, two kinds of resin glycosides, named scammonin I and II, were isolated and characterized, respectively, as (11S)-hydroxyhexadecanoic acid, 11-{[O-6-deoxy-4-O-(2(E)-methyl-1-oxo-2-butenyl)-β-d-glucopyranosyl-(1 → 4)-O-6-deoxy-2-O-(2-methyl-1-oxobutyl)-α-l-mannopyranosyl-(1 → 2)-O-β-d-glucopyranosyl-(1 → 2)-6-deoxy-β-d-glucopyranosyl]oxy}-, intramol. 1,3‴-ester and (11S)-hydroxyhexadecanoic acid, 11-{[O-β-d-glucopyranosyl-(1 → 4)-O-6-deoxy-2-O-(2-methyl-1-oxobutyl)-α-l-mannopyranosyl-(1 → 2)-O-β-d-d-glucopyranosyl-(1 → 2)-6-deoxy-β-d-glucopyranosyl]oxy}-, intramol. 1,3‴-ester.

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