Add time:07/27/2019 Source:sciencedirect.com
Stereochemical results obtained from the concomitant reduction and desulfinylation of 1-phenyl-2-pyridyl-2(p-tolysulfinyl)- and 1,2-diphenyl-2-phenylsulfinyl ethanols with lithium aluminum deuteride reveal that the reactions proceed stereospecifically via σ-sulfurane as a common intermediate.
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