Add time:07/24/2019         Source:sciencedirect.com

The diiron bisakyl complex of 9,10-ethanoanthracene-trans- 11,12-dicarboxyIic acid was obtained from the corresponding acid dichloride and Na[Fe(CO)2Cp]. Its crystal structure was determined. Photo- and thermolysis reactions were studied, giving not the expected bisalkyl complexes but elimination of the metal dimer and formation of 9,10-ethenoanthracene. The reaction of phthaloyl chloride and [Fe(CO)2Cp]− yields [Fe(CO)2Cp]2 and trans-biphthalyl.

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