Free-radical oxidation of para-substituted phenols by hypervalent tert-butylperoxyiodane and tert-butyl hydroperoxide: Synthesis of 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones-Science-Chemical Encyclopedia-lookchem

Free-radical oxidation of para-substituted phenols by hypervalent tert-butylperoxyiodane and tert-butyl hydroperoxide: Synthesis of 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones
Add time:07/26/2019 Source:sciencedirect.com

Oxidation of 4-alkylphenols 1 by 1-(tert-butylperoxy)-1,2-benziodoxol-3(1H)-one (2) in the presence of tert-butyl hydroperoxide affords selectively 4-(tert-butylperoxy)-2,5-cyclohexadien-1-ones 3 in good yields. Evidence for the involvement of free-radicals is reported.

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