Add time:07/26/2019 Source:sciencedirect.com
The stereospecific synthesis of glycoprotein processing enzyme inhibitor (+) mannostatin A 1 was achieved in ten steps from D-ribonolactone 9 (∼ 39% overall yield). The strategy featured methanesulfenyl triflate mediated intramolecular cyclization of allylic N-sufenylimidate 12.
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