Add time:07/26/2019 Source:sciencedirect.com
The absorption spectra of the α-chlorobenzyl and anilino radicals have been recorded in the vapor phase together with a new band for α-chlorobenzyl radical at shorter wavelengths (236.5 nm), probably the first Rydberg band of the radical, and subsequent reactions have been investigated by kinetic spectroscopy and gas-liquid chromatography. Flash duration time was short enough to follow the kinetics of the radical decay which occurred predominantly by bimolecular recombination. The absolute extinction coefficients are calculated from the optical densities of the absorption bands, and gas-liquid chromatography data.
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