Add time:07/26/2019 Source:sciencedirect.com
Based on the 2,2′-bipyridine-5,5′-dicarboxylic acid ligand (H2bpdc), a new metal–organic framework using holmium (cas 15125-75-4) as the coordinating metal site was synthesized through a solvothermal reaction. The 3D compound {[Ho2(bpdc)3(DMF)2]·2(DMF)}n (1) was characterized by single crystal X-ray diffraction, FTIR, TGA and PXRD. The coordination between H2bpdc, the solvent, and holmium (CN = 7) allows for the construction of a MOF containing potentially free metal sites and uncoordinated N-donor sites. These features make this MOF an attractive holmium carrier for radiotherapeutic applications.
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