Add time:07/27/2019         Source:sciencedirect.com

The oxidative addition of benzyl chloride or bromide to tetrakis(triphenylphosphine)nickel(O) followed by carbonylation and the addition of methanol yielded methyl phenylacetate. When (R)-α-D benzyl chloride was subjected to this reaction sequence, racemic ester was obtained, probably as a result of racemization in the oxidative, addition step.

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