Add time:07/30/2019 Source:sciencedirect.com
Solid-state molybdenum sulfide clusters with a nonstoichiometric sulfur-deficient site, CuxMo6S8−δ (x = 2.94 and δ ≈ 0.3) and Mo6S8–δ (δ ≈ 0.4), catalyze the dehydrogenation of cyclohexene, the hydrogenation of alkyne, alkene, aldehyde, ketone, and nitrobenzene, and the hydrogenolysis of halogenobenzenes in a hydrogen stream above 300 °C. This catalytic behavior of the clusters is similar to that of the platinum group metals, which is attributable to the isoelectronicity of sulfur-coordinating molybdenum atom to the platinum group metals.
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