Add time:08/02/2019         Source:sciencedirect.com

A new type of fluoride complex of indium(III) [N(CH3)4]6[In(H2O)6][InF6]3·18H2O (1) containing In(III) atoms in the hexafluoride complex anion and the hexaaquacomplex cation has been synthesized and structurally studied. The structure of [N(CH3)4]6[In(H2O)6][InF6]3·18H2O is formed by isolated octahedral complex [In(1)F6]3– and [In(2)F6]3– anions, octahedral complex [In(3)(H2O)6]3+ cations, [N(CH3)4]+ cations, and crystallization H2O molecules. A formation in the structure of 1 of a rather strong O–H···F hydrogen bond between the coordinated H2O molecules of the cation and F atoms of the complex anion with O···F distances of 2.472(1) Å has been established. The synthesized and structurally studied compound 1 is the obtained for the first time indium(III) fluoride complex containing a hexaaquacomplex [In(3)(H2O)6]3+ cation having the configuration of a practically ideal octahedron. The vibrational spectra of the synthesized compound have been discussed with taking into account the results of crystal structure studies.

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