Add time:07/27/2019         Source:sciencedirect.com

The iodine centered OH-adduct formed on reaction of ⋅OH radicals with 1-CHLORO-4-IODOBUTANE (cas 10297-05-9) in neutral aqueous solution transforms (k=5.4×105 s−1) to an intra-molecular radical cation (Download full-size image). The unfavorable structural conformation of solute radical cation generated on reaction of ⋅OH radicals with 1-chloro-5-iodopentane does not allow the transformation of OH-adduct into an intra-molecular radical and instead a dimer radical cation (Download full-size image) is formed.

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