Add time:07/28/2019         Source:sciencedirect.com

The complex 2-(p-dimethylaminostyryl)pyridylmethyl bis[6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolato] nickelate(III) ([DASPM][Ni(PDDT)2]) has been prepared and characterized by IR, UV-NIR and ESR. X-ray structure analysis reveals that the anions of the complex are packed in pairs and arranged as stacks along the a-axis. The shortest intermolecular S-S contact is 3.86 Å within a pair, and 4.00 Å between the pairs. The electrical conductivity measured for a compacted pellet at room temperature is 1.3 × 109 S cm1..

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