Synthesis and characterization of metal complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Ru(III), Rh(III) and Pd(II) with derivatives of 1,3,4-thiadiazole-2,5-dithiol as new ligands-Science-Chemical Encyclopedia-lookchem

Synthesis and characterization of metal complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Ru(III), Rh(III) and Pd(II) with derivatives of 1,3,4-Thiadiazole-2,5-dithiol (cas 132120-63-9) as new ligands
Add time:07/31/2019 Source:sciencedirect.com

The synthesis of some new transition metal complexes with 1,3,4-Thiadiazole-2,5-dithiol (cas 132120-63-9) derivatives (L1 and L2) as new ligands is reported. Each complex was prepared by the reaction of the ligands with the appropriate metal salts (CrCl3, MnCl2·4H2O, FeCl3, CoCl2·6H2O, NiCl2·6H2O, CuCl2·2H2O, RuCl3, RhCl3 and PdCl2). Elemental micro analysis (C.H.N.), UV–Visible spectroscopy, 1H NMR, infrared (IR) spectroscopy, atomic absorption, magnetic susceptibility, continuous variation method and molar conductance techniques were used to characterize the structural formulae of these chelate complexes.

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