Add time:07/28/2019 Source:sciencedirect.com
The vapor, liquid and CCl4 solution infrared spectra of cis- and trans-1,2-dimethoxyethylene were recorded in the region 250–4000 cm−1. The laser-Raman spectra were obtained in the liquid state only. The vibrational spectra show that at least two rotational isomers exist for each molecule. Further, the spectra indicate that for both the cis- and trans molecules, one of the rotational isomers has at least one planar conformer. Some vibrational assignments are made for the observed infrared and Raman bands of the cis- and trans- 1,2-dimethoxyethylenes.
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