Add time:08/02/2019         Source:sciencedirect.com

1,2-Bis(trimethylsiloxy)cyclobutenes undergo facile autoxidative ring contraction yielding 1-trimethylsiloxycyclopropane carboxylic acid trimethylsilyl esters as major products. The results are discussed in terms of a mechanism involving electron transfer and intermediate formation of dioxiranes.

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