Add time:07/29/2019 Source:sciencedirect.com
The crystal structure of(π-C5H5)V(CO)4 has been found from a 3-dimensional X-ray analysis. The orange crystals are orthorhombic, space group Pnma, with the vanadium atom occupying a special position on a mirror plane. The cyclopentadienyl ring was disordered ovr two equally preferred orientations. The vanadium atom and carbonyl groups are ordered. Bond lengths are compared with related structures.
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