Add time:07/11/2019         Source:sciencedirect.com

Enantioenriched, diastereomerically pure (2-carbamoyloxy-1-alkenyl)cyclopropanes 22 are easily prepared via deprotonation of different allyl carbamates with n-butyllithium and (−)-sparteine (4). The mechanism of the cyclization reaction was determined and several substituted (S)-configured vinylcyclopropanes 32 were synthesized by two different methods. The configurational stability of the intermediate lithiated allyl carbamates and the half-time of epimerization were investigated in a series of silylation experiments, achieving up to 90% ee in the kinetically controlled enantiotopos-differentiating deprotonation.

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