Add time:07/30/2019         Source:sciencedirect.com

The crotylstannation reaction: has been found to be reversible. The compounds trans/cis-Bu3-nCln SnCH2CH= CHCH3 (n = 0, 1, 2) have been prepared by elimination reactions of organostannoxy compounds,Bu3−nClnSn—O—C(Me)(i-Pr)CH(Me)CHCH2, which were synthesized by means of transalkoxylation between Bu3-nCInSn(OMe) compounds and threo/erithro-2,3,4-trimethyl-5-hexen-3-ol. Under the conditions used the elimination occurs stereospecifically and with complete allylic rearrangement. The ability of the organostannoxy compounds to yield crotyl butylchlorotins via elimination increases in the order, Bu3Sn—O—C < Bu2ClSn—O—C < BuCI2Sn—O—C. In the addition reactions, the sequence of increasing reactivity is Bu3SnCrot < CIBu2SnCrot < CI2BuSnCrot (Crot = crotyl). The 13C NMR spectra of the compounds made reveal that the chemical shifts of the allylic carbon atoms are related to the inductive effects of the chloro-substituents.

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