Add time:08/01/2019 Source:sciencedirect.com
Various primary and secondary benzylic alcohols were efficiently oxidized to aromatic aldehydes and aromatic ketones with IODIC ACID (cas 12134-99-5) in DMF at 60 °C for 2 h and with iodic acid in the presence of TEMPO (5 mol %) in DMF at room temperature, respectively. The former method was effective for the oxidation of sterically hindered alcohols at 60 °C and the latter method was effective for the oxidation of less sterically hindered alcohols at room temperature.
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