Add time:07/31/2019         Source:sciencedirect.com

By oxidation of mononuclear and dinuclear platinum(II) complexes having as ligands N4-acylated 1,2,4-triaminobutane units with H2O2 an intermediate was observed, probably a platinum bound hydroperoxide which is stabilized by hydrogen bonding to the acyl function in the side chain. Such an intermediate could not be isolated in the oxidation of [Cl2PtLLPtCl2] to the platinum(IV) complexes [(HO)2Cl2PtLLPtCl2(OH)2] (LL = 1,2,9,10-tetraaminodecane or 1,2,11,12-tetraaminododecane). The synthesis of several mononuclear and dinuclear diamine tetrachloro platinum(IV) complexes is reported.

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