Add time:08/06/2019 Source:sciencedirect.com
The synthesis of two [Hg(L1)2] and [Hg(L2)2] complexes using asymmetric triazenes as ligands are reported. The triazene ligands are substituted with cyano and chloride groups in the ortho positions of the aryl rings (where HL1 and HL2 are 1-(2-ethoxyphenyl)-3-(2-cyanophenyl)triazene and 1-(2-ethoxyphenyl)-3-(2-chlorophenyl) triazene, respectively). These complexes were prepared by the reaction of corresponding triazenes with Hg(NO3)2 and were characterized by FT-IR, NMR, elemental and single crystal X-ray analyses. Both triazene ligands were found to deprotonate on coordination and act as tridentate chelating ligands forming distorted N4O2 octahedral geometry around HgII atoms. Hydrogen bonds, π⋯π and C–H⋯π stacking interactions help to the stabilization of the resulted frameworks.
We also recommend Trading Suppliers and Manufacturers of Bis(4-cyanophenyl)methanol (cas 134521-16-7). Pls Click Website Link as below: cas 134521-16-7 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View